4.8 Article

Application of recyclable ionic liquid-supported imidazolidinone catalyst in enantioselective Diels-Alder reactions

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GREEN CHEMISTRY
卷 14, 期 9, 页码 2626-2630

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c2gc35966a

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  1. Nanyang Technological University (NTU)
  2. NTU New Initiative Funding, Ministry of Education [M45110000]
  3. A*STAR SERC Grant [0721010024]

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The application of ionic liquid-supported imidazolidinone catalyst I in enantioselective Diels-Alder reactions was investigated. The Diels-Alder reactions involving alpha,beta-unsaturated aldehydes and cyclopentadiene proceeded efficiently in the presence of catalyst I to provide the desired products in moderate to good yields with good to excellent enantioselectivities. Especially noteworthy, catalyst I can be recovered and reused for up to five runs while maintaining its high catalytic activity.

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