期刊
GREEN CHEMISTRY
卷 14, 期 5, 页码 1289-1292出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2gc00028h
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资金
- National Natural Science Foundation of China [20423002, 20923004, 21173176]
- NFFTBS [J1030415]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1036]
- State Key Laboratory of Physical Chemistry of Solid Surfaces
Using water as solvent, the oxidative kinetic resolution of a wide range of racemic secondary alcohols with a chiral PNNP/Ir catalyst was investigated. The catalytic reaction proceeded smoothly with excellent enantioselectivity (up to 97% ee) under mild conditions, providing an environmentally benign process to achieve optically active alcohols.
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