4.8 Article

Solvent free aerobic oxidation of alcohols with 1-methyl-2-azaadamantane N-oxyl as a recyclable catalyst through phase separation

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GREEN CHEMISTRY
卷 13, 期 7, 页码 1659-1663

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c1gc15076f

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  1. New Energy and Industrial Technology Development Organization (NEDO) in Japan

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An expedient, non-metallic green protocol for aerobic oxidation of alcohols was established. 1-Methyl-2-azaadamantane N-oxyl was used as the core catalyst due to its superior chemical stability and catalytic performance. The catalyst can be easily reused through phase separation by taking advantage of its solubility feature, which varies with its oxidation state.

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