4.8 Article

Heterogeneously catalysed Strecker-type reactions using supported Co(II) catalysts: microwave vs. conventional heating

期刊

GREEN CHEMISTRY
卷 13, 期 11, 页码 3282-3289

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1gc15741h

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资金

  1. Payame Noor University
  2. Sharif University of Technology
  3. Ministerio de Ciencia e Innovacion, Gobierno de Espana [RYC-2009-04199]
  4. Consejeria de Ciencia e Innovacion, Junta de Andalucia [P10-FQM-6711, P09-FQM-4781]
  5. MICINN [CTQ2008-01330]

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A range of alpha-aminonitriles could be efficiently prepared from various aldehydes/ketones and primary or secondary amines using a highly active and stable Co(II) complex supported on different mesoporous supports at both room temperature and low temperature microwave irradiation under solventless conditions. Catalysts were also highly reusable under the investigated reaction conditions and could be reused at least 10 times without loss of catalytic activity.

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