期刊
GREEN CHEMISTRY
卷 13, 期 10, 页码 2727-2733出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1gc15503b
关键词
-
资金
- EPSRC
- Thomas Swan Co. Ltd.
- EPSRC DICE
- Complutense University of Madrid [S2009AMB1588]
- Royal Society
This article explores the possibility of utilising supercritical CO2 obtained from carbon capture and storage (CCS) as a solvent and examines the hydrogenation of isophorone to 3,3,5-trimethylcyclohexanone using supercritical CO2 with added N-2, CO or H2O to emulate the contaminants expected in CO2 from CCS. None of the impurities appear to cause insuperable problems in the hydrogenation of isophorone when present at concentrations likely to be found in CO2 from CCS. N-2 introduces modest changes in phase behaviour at some pressures, while CO and H2O reduce the activity of the catalyst. However, the activity can be largely regained by increasing the reaction temperature.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据