期刊
GREEN CHEMISTRY
卷 13, 期 8, 页码 2008-2012出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1gc15265c
关键词
-
资金
- DFG [Pl 178/13-1]
We report here the ethenolysis of squalene and natural rubber utilizing (NHC)(NHCewg) RuCl2(= CRR') and Grubbs-Hoveyda complexes. 0.01 mol% [Ru] per double bond are sufficient for extensive squalene cleavage, resulting in the formation of numerous terminal olefins, which were identified by GC/MS. The depolymerization of natural rubber requires 0.1 mol% [Ru] and leads to the formation of various oligomeric isoprenes, several of which (n = 2-6) were isolated and characterized.
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