期刊
GREEN CHEMISTRY
卷 13, 期 8, 页码 2161-2166出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1gc15390k
关键词
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资金
- University of the Basque Country/Basque Government [GIC10/52/IT-370-10, S-PC10UN10]
- Spanish Ministry of Science and Innovation [CTQ2010-20703]
- University of the Basque Country (UPV/EHU)
The oxidation of secondary benzyl alcohols is catalyzed by two palladacycles at atmospheric pressure in PEG-400, a sustainable reaction media. Recycling of the active catalytic species is performed up to the 5th run, and catalyst loadings decreased down to 10(-8) mol%, thus achieving unprecedented TON and TOF values. In addition, the same conditions proved to be effective for the aerobic oxidation of benzyl methylene compounds, a scarcely explored process by palladium catalysts.
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