Natural and human-induced environmental change in southern Albania for the last 300 years - Constraints from the Lake Butrint sedimentary record

A sediment core from Lake Butrint in southwestern Albania contains an annually-layered sequence covering the last similar to 300 years. It provides thus an exceptionally well-dated time series to study past climate-driven environmental changes, as well as anthropogenic perturbations along the coast of the Ionian Sea. The varves are composed of organic-rich carbonate couplets and detritus-dominated clay layers. The first are deposited during spring-to-fall, and reflect the chemistry of the lake, which, in turn, is sensitive to 1) the relative importance of marine versus freshwater inputs, 2) relative evaporation rates, and 3) the productivity cycle within the lake. The detrital laminae are deposited during winter, reflecting precipitation and runoff conditions during the wet season. A 2-3 parts per thousand stable carbon isotope ratio shift in both bulk organics and authigenic carbonates was attributed to increasing eutrophication towards the end of the 20th century, and validated by historical and instrumental data. An increase in the delta O-18 of authigenic carbonates by more than 8 parts per thousand indicates the progressive salinization of the lake, which can primarily be attributed to man-made perturbations that reduced the freshwater input to the lake and/or enhanced the exchange with seawater from the nearby Ionian Sea. A recent increase in the relative evaporation versus precipitation rates may have additionally contributed to the observed O-18 enrichment in the Lake Butrint carbonates. The interdecadal cyclicity in the thickness of the detrital laminae seems to be at least partially controlled by NAO and/or ENSO-like phenomena that modulate precipitation patterns in the eastern Mediterranean. Thus, this study demonstrates the potential of combining microstratigraphic and stable isotopic tools to disentangle anthropogenic and natural environmental changes in Lake Butrint, validated by historical records. (C) 2009 Elsevier B.V. All rights reserved.