期刊
GEOFLUIDS
卷 12, 期 4, 页码 -出版社
WILEY-HINDAWI
DOI: 10.1111/j.1468-8123.2012.00369.x
关键词
acid gas; CO2; contact angles; geological storage; H2S; rock wettability
资金
- Conseil Regional d'Aquitaine
- Total
- Agence Nationale de la Recherche
The various modes of acid gas storage in aquifers, namely structural, residual, and local capillary trapping, are effective only if the rock remains water-wet. This paper reports an evaluation, by means of the captive-bubble method, of the water-wet character in presence of dense acid gases (CO2, H2S) of typical rock-forming minerals such as mica, quartz, calcite, and of a carbonate-rich rock sampled from the caprock of a CO2 storage reservoir in the South-West of France. The method, which is improved from that previously implemented with similar systems by Chiquet et al. (Geofluids 2007; 7: 112), allows the advancing and receding contact angles, as well as the adhesion behavior of the acid gas on the mineral substrate, to be evaluated over a large range of temperatures (up to 140 degrees C), pressures (up to 150 bar), and brine salinities (up to NaCl saturation) representative of various geological storage conditions. The water-receding (or gas-advancing) angle that controls structural and local capillary trapping is observed to be not significantly altered in the presence of dense CO2 or H2S. In contrast, some alteration of the water-advancing (or gas-receding) angle involved in residual trapping is observed, along with acid gas adhesion, particularly on mica. A spectacular wettability reversal is even observed with mica and liquid H2S. These results complement other recent observations on similar systems and present analogies with the wetting behavior of crude oil/brine/mineral systems, which has been thoroughly studied over the past decades. An insight is given into the interfacial forces that govern wettability in acid gas-bearing aquifers, and the consequences for acid gas geological storage are discussed along with open questions for future work.
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