High-precision U-Pb zircon age calibration of the global Carboniferous time scale and Milankovitch band cyclicity in the Donets Basin, eastern Ukraine

High-precision ID-TIMS U-Pb zircon ages for 12 interstratified tuffs and tonsteins are used to radiometrically calibrate the detailed lithostratigraphic, cyclostratigraphic, and biostratigraphic framework of the Carboniferous Donets Basin of eastern Europe. Chemical abrasion of zircons, use of the internationally calibrated EARTHTIME mixed U-Pb isotope dilution tracer, and improved mass spectrometry guided by detailed error analysis have resulted in an age resolution of <0.05%, or similar to 100 ka, for these Carboniferous volcanics. This precision allows the resolution of time in the Milankovitch band and confirms the long-standing hypothesis that individual high-frequency Pennsylvanian cyclothems and bundles of cyclothems into fourth-order sequences are the eustatic response to orbital eccentricity (similar to 100 and 400 ka) forcing. Tuning of the fourth-order sequences in the Donets Basin to the long-period eccentricity cycle results in a continuous age model for the Middle to Late Pennsylvanian (Moscovian-Kasimovian-Ghzelian) strata of the basin and their record of biological and climatic changes through the latter portion of the late Paleozoic Ice Age. Detailed fusulinid and conodont zonations allow the export of this age model to sections throughout Euramerica. Additional ages for Mississippian strata provide among the first robust radiometric calibration points within this subperiod and result in variable lowering of the base ages of its constituent stages compared to recent global time scale compilations.