期刊
FUNCTIONAL MATERIALS LETTERS
卷 7, 期 3, 页码 -出版社
WORLD SCIENTIFIC PUBL CO PTE LTD
DOI: 10.1142/S1793604714500209
关键词
Sulfur/cobaltosic oxide composite; lithium sulfur battery; electrochemical performances
资金
- National Natural Science Foundation of China [21173198]
- Science and Technology Support Program of Hubei Province, China [2013BHE014]
To improve the overall electrochemical performance of the sulfur cathode in Li/S batteries, a hollow Co3O4 nanotube with a channel measuring approximately 12.5 nm in diameter is synthesized and then impregnated with sulfur via a melt-diffusion strategy. X-ray powder diffraction (XRD), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET) analysis and thermogravimetric analysis indicate that sulfur impregnated the channels of the hollow Co3O4 nanotube. Because the sulfur is mostly restricted to the Co3O4 nanotubes, a sulfur/Co3O4 cathode with 10 wt.% sulfur loading delivers an initial discharge capacity of 963.4 mAh g(-1), with much of the capacity contributed by Co3O4, and exhibits excellent reversibility with a capacity reservation of 80.8% after 100 cycles.
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