Article
Electrochemistry
Krishnaveni Palanisamy, Sven Daboss, David Schaefer, Marcus Rohnke, Laurin Derr, Marcel Lang, Rolf Schuster, Christine Kranz
Summary: This study presents a cost-effective spray-coating process for the preparation of HC composite electrodes for sodium-ion batteries. The spray-coated anodes showed improved performance compared to doctor bladed anodes, indicating the potential of this method for practical applications.
BATTERIES & SUPERCAPS
(2023)
Article
Chemistry, Physical
Jannes Mueller, Mozaffar Abdollahifar, Stefan Doose, Peter Michalowski, Nae-Lih Wu, Arno Kwade
Summary: This study scaled up the production process of silicon/graphite composites and investigated the effects of carbon coating and calendering on the particle level. The study found that carbon coating reduces surface area, stabilizes the composite, and enhances electrical conductivity. The electrochemical performance of the composites showed improved capacity retention with carbon coating, especially after calendering.
JOURNAL OF POWER SOURCES
(2022)
Article
Chemistry, Physical
Fanhao Tang, Dongxu He, Hao Jiang, Rongshuo Wang, Zheling Li, Weidong Xue, Rui Zhao
Summary: In this study, a top-down strategy was presented to directly fabricate GO/graphite foam from graphite paper. The synergistic effect with GO and graphite greatly enhanced the electrochemical performance of the electrode.
Article
Electrochemistry
Thi BeTa Truong, Ying-Ru Chen, Guan-Yin Lin, Han -Tu Lin, Yi-Shiuan Wu, Chun-Chen Yang
Summary: In this study, LiPAA-coated Gr/Si/C composite materials were prepared and showed improved capacity retentions during cycling tests. The LiPAA polymer coating stabilized the interface structure between the electrode and the electrolyte during the cycling process.
ELECTROCHIMICA ACTA
(2021)
Article
Chemistry, Multidisciplinary
Peng Shi, Li-Peng Hou, Cheng-Bin Jin, Ye Xiao, Yu-Xing Yao, Jin Xie, Bo-Quan Li, Xue-Qiang Zhang, Qiang Zhang
Summary: This study proposes a successive conversion-deintercalation (CTD) delithiation mechanism to restrain the generation of dead Li by manipulating the overpotential of the anode. The working batteries based on this mechanism show improved cycling performance and capacity retention under practical conditions.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Physical
Christopher L. Berhaut, Marta Mirolo, Diana Zapata Dominguez, Isaac Martens, Stephanie Pouget, Nathalie Herlin-Boime, Marion Chandesris, Samuel Tardif, Jakub Drnec, Sandrine Lyonnard
Summary: This study investigates the distribution of lithiated phases in a silicon-graphite composite anode using correlative operando SAXS and WAXS tomography. It reveals in-plane and out-of-plane inhomogeneities during cycling and relaxation processes, showing lithium concentration gradients and charge redistribution between different regions. These results highlight the importance of considering heterogeneous reaction processes and charge dynamics for modeling the durability of high capacity Li-ion batteries.
ADVANCED ENERGY MATERIALS
(2023)
Article
Engineering, Chemical
Debabrata Mohanty, Yi-Hung Wang, Ya-Chen Tsai, I-Ming Hung
Summary: Vanadium oxide is an environmentally friendly material, but its economic utilization is challenging due to the inability to control the size of etched holes. In this study, copper/graphite felt composite electrodes with controllable hole depth were prepared by electrodeposition and etching. The composite electrodes exhibited good material characteristics and electrochemical performance under specific etching temperature and time conditions.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2023)
Article
Nanoscience & Nanotechnology
Mozaffar Abdollahifar, Andrey Vinograd, Chia-Yang Lu, Shu-Jui Chang, Jannes Mueller, Lars Frankenstein, Tobias Placke, Arno Kwade, Martin Winter, Chi-Yang Chao, Nae-Lih Wu
Summary: In this study, a multifunctional polymeric artificial solid-electrolyte interphase (A-SEI) protective layer was developed on carbon-coated Si@Gr anode particles to solve the long cycling stability challenge of Si@Gr composites. The coating made of sulfonated chitosan (SCS) was found to enhance ionic conduction and mechanical strength, leading to a superior long cycle life performance of the anodes.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
You Jin Kim, SeongJi Pyo, Suji Kim, Won-Hee Ryu
Summary: This study presents a synthetic strategy to increase the interlayer distance of graphite by embedding metallic pillars between graphene layers, facilitating Na+ ion intercalation and enhancing battery performance. The reconstructed W-rGO anodes exhibit high capacity and excellent performance, showing great potential for the realization of Na-ion battery technology.
Article
Nanoscience & Nanotechnology
Wen Zhang, Siwei Gui, Wanming Li, Shuibin Tu, Guocheng Li, Yun Zhang, Yongming Sun, Jingying Xie, Huamin Zhou, Hui Yang
Summary: This study proposed a multilayer coating method for the fabrication of functionally gradient Si/graphite composite electrodes, which effectively mitigated the volume change-caused structural degradation and realized high capacity in lithium-ion batteries. The PG-Si/Gr electrode exhibited excellent stability and high reversible capacity, even at high mass loadings. When paired with a commercial NCM532 cathode, the PG-Si/Gr||NCM532 full cell demonstrated a stable areal capacity after cycling.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Ling Fan, Huabin Xie, Yanyao Hu, Zhuoma Caixiang, Apparao M. M. Rao, Jiang Zhou, Bingan Lu
Summary: This study demonstrates a low-concentration, non-flammable, and weakly solvating electrolyte that enhances the safety and cyclability of potassium ion batteries.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Jens Matthies Wrogemann, Lukas Haneke, Thrinathreddy Ramireddy, Joop Enno Frerichs, Irin Sultana, Ying Ian Chen, Frank Brink, Michael Ryan Hansen, Martin Winter, Alexey M. Glushenkov, Tobias Placke
Summary: Dual-graphite batteries (DGBs) have gained attention as a low-cost technology for stationary energy storage. This study introduces a composite of black phosphorus with carbon (BP-C) as the negative electrode material for dual-ion batteries (DIBs) and investigates its electrochemical behavior.
Article
Electrochemistry
Lukas Medenbach, Lea C. Meyer, Andrea Balducci
Summary: This study reports the first use of TMG and TEG solvents in potassium-based systems, demonstrating their effectiveness in intercalating and extracting potassium ions reversibly. The graphite electrodes with 1.5 M KFSI in TEG/VEC electrolyte exhibit stable intercalation capacity of 200 mAh g-1 for 40 cycles at C/10, comparable to conventional organic electrolytes.
ELECTROCHEMISTRY COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Seoin Back, Seung-Ho Yu, Yuanzhe Piao, Juhyung Choi, Aihua Jin, Hyun Dong Jung, Dongjin Ko, Ji Hyun Um, Yoon Choi, So Hee Kim
Summary: This study presents a novel nanoarchitecture of nitrogen and sulfur co-doped graphene nanoribbons, which exhibit high capacity and stable cycling performance as anodes for potassium-ion batteries. Theoretical calculations demonstrate that graphene nanoribbons with NS co-doping have improved potassium-ion intercalation properties compared to parallel-edged nanoribbons.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Thrinathreddy Ramireddy, Jens Matthies Wrogemann, Lukas Haneke, Irin Sultana, Felipe Kremer, Ying Ian Chen, Martin Winter, Tobias Placke, Alexey M. Glushenkov
Summary: Dual-ion batteries (DIBs) with high operating voltage and potential in energy storage applications are attracting attention. Antimony in the form of a composite with carbon (Sb-C) is evaluated as an anode material for DIB full cells for the first time. Sb-C full cells exhibit maximum estimated specific energies of 290 Wh/kg (based on electrode masses) and 154 Wh/kg (based on the combined mass of electrodes and active salt), expanding knowledge on DIBs with non-graphitic anodes.
Article
Electrochemistry
Marco Renzi, Francesco Nobili, Krzysztof Miecznikowski, Aldona Kostuch, Anna Wadas, Iwona A. Rutkowska, Pawel J. Kulesza
Summary: The study evaluated the catalytic activity of commercial carbon-supported PtFe nanoparticles combined with mesoporous polyoxometalate Cs3H3PMo9V3O40 towards the oxygen reduction reaction in acid medium. The composite catalyst showed good performance with low Pt loading during ORR, leading to noticeable improvements in fuel cell behavior especially at low relative humidity conditions. Accelerated stress test demonstrated that the proposed catalytic system exhibited stable performance and good morphological rigidity after initial losses.
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
(2022)
Correction
Electrochemistry
Pawel J. Kulesza, Francesco Nobili, Sonia Dsoke, Vito Di Noto, Iwona A. Rutkowska
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Maider Zarrabeitia, Francesco Nobili, Oier Lakuntza, Javier Carrasco, Teofilo Rojo, Montse Casas-Cabanas, Miguel Angel Munoz-Marquez
Summary: This article investigates the factors contributing to the capacity fading of P2-Na-2/3[Fe1/2Mn1/2]O-2 cathode material for sodium-ion batteries. Through experimental and theoretical analysis, it is found that the observed capacity fading is mainly attributed to the structural phase transition at high voltage, which leads to an increase in bulk electronic resistance.
COMMUNICATIONS CHEMISTRY
(2022)
Article
Nanoscience & Nanotechnology
Leonardo Sbrascini, Antunes Staffolani, Luca Bottoni, Hamideh Darjazi, Luca Minnetti, Marco Minicucci, Francesco Nobili
Summary: The effects of a biomass-derived hard carbon matrix and a sustainable cross-linked binder as electrode components for a silicon-based anode were investigated to reduce capacity fade caused by volume expansion and shrinkage. Results showed an effective buffering of volume changes, retention of structural and interfacial integrity, high capacity performance, and good rate capability.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Energy & Fuels
Antunes Staffolani, Arianna Baldinelli, Gianni Bidini, Francesco Nobili, Linda Barelli
Summary: The increasing demand for technological solutions for the energy transition is driving the development of decarbonised systems, including Solid Oxide Cells. This paper investigates the impedance contributions in commercial-sized Solid Oxide Cells under different reactant feed gases, providing valuable insights for the diagnosis and improvement of the technology.
Editorial Material
Chemistry, Multidisciplinary
Mario Marinaro, Sonia Dsoke
Article
Chemistry, Physical
Qiang Fu, Anna-Lena Hansen, Bjorn Schwarz, Angelina Sarapulova, Lihua Zhu, Guiying Tian, Martin Etter, Alexander Missyul, Edmund Welter, Vadim Murzin, Sylvio Indris, Raheleh Azmi, Michael Knapp, Sonia Dsoke, Helmut Ehrenberg
Summary: Cation-doped V2O5 with different elements M (M = Mn, Ni, and Fe) were successfully synthesized via a hydrothermal method, revealing the impact of doping cations on the local structure of V2O5. Although the exact position of the doping cations was not directly determined, the results suggest that the doping cations may prefer to reside in the interstitial positions rather than the substitutional positions.
CHEMISTRY OF MATERIALS
(2022)
Article
Electrochemistry
Sandra Schrade, Zijian Zhao, Zhazira Supiyeva, Xinman Chen, Sonia Dsoke, Qamar Abbas
Summary: The study extends the working temperature range of MnO2/activated carbon supercapacitors by using a concentrated choline nitrate-based electrolyte. The hierarchical electrode design enables efficient operation even at low temperatures.
ELECTROCHIMICA ACTA
(2022)
Article
Chemistry, Multidisciplinary
Chengping Li, Kristina Pfeifer, Xianlin Luo, Georgian Melinte, Jinsong Wang, Zhengfu Zhang, Yingjie Zhang, Peng Dong, Angelina Sarapulova, Helmut Ehrenberg, Sonia Dsoke
Summary: Sodium-ion and potassium-ion batteries are potential alternatives to lithium-ion batteries in energy storage, with advantages of abundance and low cost of Na and K. However, the large size of Na+/K+ causes volume change of the hosting material, resulting in capacity decay. In this study, porous few-layer SnS2 nanosheets are grown on reduced graphene oxide, forming a SnS2-rGO sandwich structure. This nanostructure enables high and stable electrochemical cycling performance of SnS2-rGO. The effects of different conductive carbons and electrolyte additive on the electrochemical performance are also evaluated. This work provides guidelines for better NIBs and KIBs through optimized electrode structure, electrolyte additives, and carbon additives.
Article
Electrochemistry
Hamideh Darjazi, Inaki Madinabeitia, Maider Zarrabeitia, Elena Gonzalo, Begona Acebedo, S. Javad Rezvani, Francisco Jose Fernandez-Carretero, Francesco Nobili, Alberto Garcia-Luis, Miguel Angel Munoz-Marquez
Summary: A novel mid-frequency alternating current dual magnetron sputtering method was used to prepare various LNMO thin films with highly controlled morphology and particle size. The N-containing LNMO thin film electrodes exhibited enhanced cycling and rate performance, with up to 15% increased discharge capacity at 1 C and outstanding rate performance up to 10 C. The complex phase transitions observed in standard LNMO electrodes were almost suppressed in N-containing LNMO thin films grown under different Ar-N-2 gas flow mixtures, as indicated by electrochemical impedance spectroscopy results.
Article
Electrochemistry
Luca Minnetti, Vittorio Marangon, Paolo Andreotti, Antunes Staffolani, Francesco Nobili, Jusef Hassoun
Summary: This study synthesized a layered LiNi0.2Co0.2Al0.1Mn0.45O2 cathode and investigated its properties. The morphology of the composite powder was examined using scanning electron microscopy (SEM), and the achieved stoichiometry was confirmed using energy dispersive X-ray spectroscopy (EDS) and Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). X-ray diffraction (XRD) identified the layered structure unit cell, while Raman spectroscopy revealed the motions of M-O bonds. The electrochemical process of LiNi0.2Co0.2Al0.1Mn0.45O2 in a lithium half-cell was characterized by an irreversible oxidation at 4.6 V vs. Li+/Li and a reversible Li (de)intercalation at 3.8 V vs. Li+/Li. A proof-of-concept Li-ion battery utilizing the LiNi0.2Co0.2Al0.1Mn0.45O2 cathode and a silicon oxide composite (SiOx-C) anode without any pretreatment demonstrated a cycling behavior strongly influenced by the anode/cathode ratio.
ELECTROCHIMICA ACTA
(2023)
Article
Electrochemistry
Fatemehsadat Rahide, Eugen Zemlyanushin, Georg-Maximilian Bosch, Sonia Dsoke
Summary: Among possible beyond Lithium candidates, Aluminum is the most abundant one, with the capability of providing three times more charge per redox center compared to Lithium. However, the requirement of a corrosive acidic electrolyte based on AlCl3 restricts its practical use. Recently, Al(OTF)(3) has been proposed as a non-corrosive alternative, but its electrochemical behavior and reversibility of redox reactions need further evaluation.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2023)
Article
Electrochemistry
Luca Bottoni, Hamideh Darjazi, Leonardo Sbrascini, Antunes Staffolani, Serena Gabrielli, Genny Pastore, Alessia Tombesi, Francesco Nobili
Summary: Corncobs are used as raw materials for the preparation of hard carbon and synthesis of carboxymethyl cellulose (CMC) binder in sodium-ion batteries (SIBs). The corncob-derived electrodes exhibit high discharge capacity, good capacity retention, and promising rate capability. The study also provides new insights into the sodium storage behavior of Hard Carbons, revealing a capacitive process in the sloping voltage region and a diffusion-controlled intercalation in the low-voltage plateau.
Article
Chemistry, Multidisciplinary
Qiang Fu, Bjoern Schwarz, Ziming Ding, Angelina Sarapulova, Peter G. Weidler, Alexander Missyul, Martin Etter, Edmund Welter, Weibo Hua, Michael Knapp, Sonia Dsoke, Helmut Ehrenberg
Summary: Polyanion-type phosphate materials, like M3V2(PO4)(3) (M = Li/Na/K), show promise as negative electrodes for monovalent-ion batteries. However, understanding the reaction mechanisms during monovalent-ion insertion remains a challenge.
Article
Green & Sustainable Science & Technology
H. Darjazi, L. Bottoni, H. R. Moazami, S. J. Rezvani, L. Balducci, L. Sbrascini, A. Staffolani, A. Tombesi, F. Nobili
Summary: Biomass-derived hard carbon materials have gained attention for their abundance, low cost, high performance, and fast regeneration. In this study, olive leaves were used to synthesize hard carbon and its performance as an electrode material for Li-ion batteries, Na-ion batteries, and supercapacitors was evaluated. The results showed that the olive leaves-derived hard carbon exhibited promising cycling stability and high energy and power capabilities.
MATERIALS TODAY SUSTAINABILITY
(2023)