Article
Construction & Building Technology
Saif Al-Shmaisani, Ryan D. Kalina, Raissa Douglas Ferron, Maria C. G. Juenger
Summary: The availability of traditional siliceous Class F fly ash is decreasing as countries switch to renewable energy sources. To extend the availability of siliceous fly ash, suppliers are distributing blended coal ashes and incorporating other coal combustion products (CCPs) or natural pozzolans. While the characteristics of these blended fly ashes may differ, they perform well in cement-based mixtures.
CONSTRUCTION AND BUILDING MATERIALS
(2022)
Article
Polymer Science
Himawan Tri Bayu Murti Petrus, Muhammad Olvianas, Muhammad Faiz Shafiyurrahman, I. Gusti Agung Arvin Nanda Pratama, Siti Nurul Aisyiyah Jenie, Widi Astuti, Muhammad Istiawan Nurpratama, Januarti Jaya Ekaputri, Ferian Anggara
Summary: The study of geopolymers in the infrastructure sector has gained attention due to their environmentally friendly properties and lower energy requirements. This study investigates the synthesis of geopolymers using fly ash and geothermal silica-based dry activator, and analyzes the effects of curing time and temperature on compressive strength.
Article
Chemistry, Physical
Ewelina Grabias-Blicharz, Rafal Panek, Malgorzata Franus, Wojciech Franus
Summary: Mechanically treated fly ash was used to provide Al and Si atoms for zeolite synthesis. The combination of mechanical activation and hydrothermal synthesis improved the dissolution of activated fly ash and the crystallization of zeolites. The obtained zeolite materials exhibited high crystallinity and a large specific surface area. This study provides important data for utilizing fly ash resources and synthesizing practical zeolites.
Article
Construction & Building Technology
E. R. Teixeira, A. Camoes, F. G. Branco
Summary: Sustainable construction is important, especially in terms of building materials. Using biomass fly ash as a cement replacement material in high-volume fly ash concrete can improve its properties and contribute positively to its quality, durability, and sustainability.
CONSTRUCTION AND BUILDING MATERIALS
(2022)
Article
Construction & Building Technology
Mahdi Rafieizonooz, Elnaz Khankhaje, Shahabaldin Rezania
Summary: Coal power plant wastes and coal ash concrete have the potential to replace cement and fine aggregate, allowing for the production of sustainable and environmentally friendly concrete with reduced cost and natural resource utilization.
JOURNAL OF BUILDING ENGINEERING
(2022)
Article
Construction & Building Technology
Bingchuan Cheng, Rentai Liu, Xiuhao Li, Enrique del Rey Castillo, Mengjun Chen, Shucai Li
Summary: Increasing FA/CBA values can improve the performance of backfill materials, but the excellent water retention of CBA may reduce drainage capacity. A 0.5% superplasticizer and a 30%-50% FA/CBA ratio can meet the requirements and have been applied in a filling mining project.
CONSTRUCTION AND BUILDING MATERIALS
(2022)
Article
Engineering, Chemical
Ashraff Aziz Marhoon, Siti Aishah Hasbullah, N. Asikin-Mijan, Wan Nur Aini Wan Mokhtar
Summary: Treated fly ash (TCFA) can efficiently synthesize high-purity, single-phase zeolite-X and remove Ni and V ions from aqueous solutions. The pretreatment process involves magnetic fraction separation and acid washing, followed by fusion and hydrothermal treatment to synthesize zeolites. The zeolite product exhibits high crystallinity, purity, and thermal stability, and can adsorb Ni and V through chemical adsorption mechanisms.
ADVANCED POWDER TECHNOLOGY
(2023)
Article
Engineering, Environmental
Nannan Wang, Liangwei Li, Yuhang Zhang, Yanhe Han, Zaixing Li
Summary: Fe2O3/CFA, prepared by loading Fe2O3 onto raw coal fly ash (RCFA), exhibits excellent catalytic performance in the treatment of refractory organic wastewater, showing high removal efficiency for p-nitrophenol (PNP) simulated wastewater under optimal conditions. The Fenton-like process involves the generation of various reactive oxygen species, with hydroxyl radicals (center dot OH) playing a crucial role in PNP degradation. Fe2O3/CFA maintains its catalytic capability in the advanced treatment of real coking wastewater, and further optimization of the preparation process can reduce the treatment cost.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Engineering, Environmental
Zhikun Zhang, Yanli Wang, Yuqi Zhang, Boxiong Shen, Jiao Ma, Lina Liu
Summary: This study investigated the stabilization behavior of heavy metals in hazardous municipal solid waste incineration fly ash (FA) using coal fly ash (CFA) as an additive via hydrothermal treatment. The results showed that most heavy metals were stabilized in the hydrothermal product, and the addition of CFA resulted in the reduction of leaching concentrations and risk assessment code (RAC) of heavy metals. The method with 30% CFA exhibited the most superior performance.
Article
Construction & Building Technology
Jan Fort, Jiri Sal, Radek Sevcik, Magdalena Dolezelova, Martin Keppert, Milos Jerman, Martina Zaleska, Vojtech Stehel, Robert Cerny
Summary: The tightening of environmental standards in the EU presents a significant push towards the transition to a circular economy. However, the use of coal fly ash as partial cement replacement may face challenges in the future, leading to the consideration of biomass fly ash as a promising alternative.
CONSTRUCTION AND BUILDING MATERIALS
(2021)
Article
Construction & Building Technology
Sepehr Seyedian Choubi, Cagla Meral Akgul
Summary: This study investigates the impact of heat exposure on the performance of alkali-activated coal fly ashes (AAF). The results show that the mechanical performance varies depending on the exposure temperature and intrinsic properties of the activated ashes. Low-Ca AAFs are found to be more stable compared to high-Ca AAFs. Heat exposure also significantly reduces the thermal conductivity and volumetric specific capacity of all AAFs.
JOURNAL OF BUILDING ENGINEERING
(2022)
Article
Engineering, Environmental
Xinyuan Zhan, Gunvor Marie Kirkelund
Summary: The study explored the use of electrodialytic remediation (ED) as a pre-treatment to remove heavy metals from MSWI fly ash before geopolymerization. The pre-treatment increased the reactivity of Si and Si/Al ratio in fly ash. A mixture of 80% coal fly ash and 20% ED treated fly ash with 8 M NaOH was found to have optimal compressive strength in geopolymerization.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Energy & Fuels
Binoy K. Saikia, James C. Hower, Nazrul Islam, Arpita Sharma, Pradeep Das
Summary: This study investigates the chemical, geological characteristics, and mineral composition of coal and its generated fly ash, exploring environmental issues and the potential recovery of rare earth elements. The results show abundant minerals such as quartz, kaolinite, and haematite in both coal and fly ash, with exceptionally high levels of certain elements.
Article
Green & Sustainable Science & Technology
Weihua Peng, Yingying Liu, Manli Lin, Yan Liu, Cheng Zhu, Linhua Sun, Herong Gui
Summary: The study found that heavy metal concentrations in leachates from coal fly ash and coal gangue were low, but still inhibited the survival and reproduction of Daphnia magna. The toxicity of the leachates to D. magna was influenced by the chemical composition of the leachates and the properties of the coal fly ash and coal gangue.
JOURNAL OF CLEANER PRODUCTION
(2022)
Article
Environmental Sciences
Tsugumi Seki, Kengo Nakamura, Yasumasa Ogawa, Chihiro Inoue
Summary: Coal fly ash (CFA) is a useful recycled resource for applications such as cement production. A study in Japan examined the leaching concentration range of toxic elements such as arsenic and selenium in different types of CFA. The study found that the leaching processes of these elements in CFA changed over time depending on environmental conditions, highlighting the importance of managing and evaluating safety for effective utilization of CFA.
ENVIRONMENTAL MONITORING AND ASSESSMENT
(2021)
Article
Energy & Fuels
Yingna Du, Chen Huang, Wei Jiang, Qiangwei Yan, Yongfei Li, Gang Chen
Summary: In this study, anionic surfactants modified hydrotalcite was used as a flow improver for crude oil under low-temperature conditions. The modified hydrotalcite showed a significant viscosity reduction effect on crude oil. The mechanism of the modified hydrotalcite on viscosity and pour point of crude oil was explored through characterization and analysis of the modified hydrotalcite and oil samples.
Article
Energy & Fuels
Mohammad Saeid Rostami, Mohammad Mehdi Khodaei
Summary: In this study, a hybrid structure, MIL-53(Al)@MWCNT, was synthesized by combining MIL-53(Al) particles and -COOH functionalized multi-walled carbon nanotube (MWCNT). The hybrid structure was then embedded in a polyethersulfone (PES) polymer matrix to prepare a mixed matrix membrane (MMM) for CO2/CH4 and CO2/N2 separation. The addition of MWCNTs prevented MIL-53(Al) aggregation, improved membrane mechanical properties, and enhanced gas separation efficiency.
Article
Energy & Fuels
Yunlong Li, Desheng Huang, Xiaomeng Dong, Daoyong Yang
Summary: This study develops theoretical and experimental techniques to determine the phase behavior and physical properties of DME/flue gas/water/heavy oil systems. Eight constant composition expansion (CCE) tests are conducted to obtain new experimental data. A thermodynamic model is used to accurately predict saturation pressure and swelling factors, as well as the phase boundaries of N2/heavy oil systems and DME/CO2/heavy oil systems, with high accuracy.
Article
Energy & Fuels
Morteza Afkhamipour, Ebad Seifi, Arash Esmaeili, Mohammad Shamsi, Tohid N. Borhani
Summary: Non-conventional amines are being researched worldwide to overcome the limitations of traditional amines like MEA and MDEA. Adequate process and thermodynamic models are crucial for understanding the applicability and performance of these amines in CO2 absorption, but studies on process modeling for these amines are limited. This study used rate-based modeling and Deshmukh-Mather method to model CO2 absorption by DETA solution in a packed column, validated the model with experimental data, and conducted a sensitivity analysis of mass transfer correlations. The study also compared the CO2 absorption efficiency of DETA solution with an ionic solvent [bmim]-[PF6] and highlighted the importance of finding optimum operational parameters for maximum absorption efficiency.
Article
Energy & Fuels
Arastoo Abdi, Mohamad Awarke, M. Reza Malayeri, Masoud Riazi
Summary: The utilization of smart water in EOR operations has gained attention, but more research is needed to understand the complex mechanisms involved. This study investigated the interfacial tension between smart water and crude oil, considering factors such as salt, pH, asphaltene type, and aged smart water. The results revealed that the hydration of ions in smart water plays a key role in its efficacy, with acidic and basic asphaltene acting as intrinsic surfactants. The pH also influenced the interfacial tension, and the aged smart water's interaction with crude oil depended on asphaltene type, salt, and salinity.
Article
Energy & Fuels
Dongao Zhu, Kun Zhu, Lixian Xu, Haiyan Huang, Jing He, Wenshuai Zhu, Huaming Li, Wei Jiang
Summary: In this study, cobalt-based metal-organic frameworks (Co-based MOFs) were used as supports and co-catalysts to confine the NHPI catalyst, solving the leaching issue. The NHPI@Co-MOF with carboxyl groups exhibited stronger acidity and facilitated the generation of active oxygen radicals O2•, resulting in enhanced catalytic activity. This research provides valuable insights into the selection of suitable organic linkers and broadens the research horizon of MOF hybrids in efficient oxidative desulfurization (ODS) applications.
Article
Energy & Fuels
Edwin G. Hoyos, Gloria Amo-Duodu, U. Gulsum Kiral, Laura Vargas-Estrada, Raquel Lebrero, Rail Munoz
Summary: This study investigated the impact of carbon-coated zero-valent nanoparticle concentration on photosynthetic biogas upgrading. The addition of nanoparticles significantly increased microalgae productivity and enhanced nitrogen and phosphorus assimilation. The presence of nanoparticles also improved the quality of biomethane produced.
Article
Energy & Fuels
Yao Xiao, Asma Leghari, Linfeng Liu, Fangchao Yu, Ming Gao, Lu Ding, Yu Yang, Xueli Chen, Xiaoyu Yan, Fuchen Wang
Summary: Iron is added as a flocculant in wastewater treatment and the hydrothermal carbonization (HTC) of sludge produces wastewater containing Fe. This study investigates the effect of aqueous phase (AP) recycling on hydrochar properties, iron evolution and environmental assessment during HTC of sludge. The results show that AP recycling process improves the dewatering performance of hydrochar and facilitates the recovery of Fe from the liquid phase.
Article
Energy & Fuels
He Liang, Tao Wang, Zhenmin Luo, Jianliang Yu, Weizhai Yi, Fangming Cheng, Jingyu Zhao, Xingqing Yan, Jun Deng, Jihao Shi
Summary: This study investigated the influence of inhibitors (carbon dioxide, nitrogen, and heptafluoropropane) on the lower flammability limit of hydrogen and determined the critical inhibitory concentration needed for complete suppression. The impact of inhibitors on explosive characteristics was evaluated, and the inhibitory mechanism was analyzed with chemical kinetics. The results showed that with the increase of inhibitor quantity, the lower flammability limit of hydrogen also increased. The research findings can contribute to the safe utilization of hydrogen energy.
Article
Energy & Fuels
Zonghui Liu, Zhongze Zhang, Yali Zhou, Ziling Wang, Mingyang Du, Zhe Wen, Bing Yan, Qingxiang Ma, Na Liu, Bing Xue
Summary: In this study, high-performance solid catalysts based on phosphotungstic acid (HPW) supported on Zr-SBA-15 were synthesized and evaluated for the one-pot conversion of furfural (FUR) to γ-valerolactone (GVL). The catalysts were characterized using various techniques, and the ratio of HPW and Zr was found to significantly affect the selectivity of GVL. The HPW/Zr-SBA-15 (2-4-15) catalyst exhibited the highest GVL yield (83%) under optimized reaction conditions, and it was determined that a balance between Bronsted acid sites (BAS) and Lewis acid sites (LAS) was crucial for achieving higher catalytic performance. The reaction parameters and catalyst stability were also investigated.
Article
Energy & Fuels
Michael Stoehr, Stephan Ruoff, Bastian Rauch, Wolfgang Meier, Patrick Le Clercq
Summary: As part of the global energy transition, an experimental study was conducted to understand the effects of different fuel properties on droplet vaporization for various conventional and alternative fuels. The study utilized a flow channel to measure the evolution of droplet diameters over time and distance. The results revealed the temperature-dependent effects of physical properties, such as boiling point, liquid density, and enthalpy of vaporization, and showed the complex interactions of preferential vaporization and temperature-dependent influences of physical properties for multi-component fuels.
Article
Energy & Fuels
Yuan Zhuang, Ruikang Wu, Xinyan Wang, Rui Zhai, Changyong Gao
Summary: Through experimental validation and optimization of the chemical kinetic model, it was found that methanol can accelerate the oxidation reaction of ammonia, and methanol can be rapidly oxidized at high concentration. HO2 was found to generate a significant amount of OH radicals, facilitating the oxidation of methanol and ammonia. Rating: 7.5/10.
Article
Energy & Fuels
Radwan M. EL-Zohairy, Ahmed S. Attia, A. S. Huzayyin, Ahmed I. EL-Seesy
Summary: This paper presents a lab-scale experimental study on the impact of diethyl ether (DEE) as an additive to waste cooking oil biodiesel with Jet A-1 on combustion and emission features of a swirl-stabilized premixed flame. The addition of DEE to biodiesel significantly affects the flame temperature distribution and emissions. The W20D20 blend of DEE, biodiesel, and Jet A-1 shows similar flame temperature distribution to Jet A-1 and significantly reduces UHC, CO, and NOx emissions compared to Jet A-1.
Article
Energy & Fuels
Jiang Bian, Ziyuan Zhao, Yang Liu, Ran Cheng, Xuerui Zang, Xuewen Cao
Summary: This study presents a novel method for ammonia separation using supersonic flow and develops a mathematical model to investigate the condensation phenomenon. The results demonstrate that the L-P nucleation model accurately characterizes the nucleation process of ammonia at low temperatures. Numerical simulations also show that increasing pressure and concentration can enhance ammonia condensation efficiency.
Article
Energy & Fuels
Shiyuan Pan, Xiaodan Shi, Beibei Dong, Jan Skvaril, Haoran Zhang, Yongtu Liang, Hailong Li
Summary: Integrating CO2 capture with biomass-fired combined heat and power (bio-CHP) plants is a promising method for achieving negative emissions. This study develops a reliable data-driven model based on the Transformer architecture to predict the flowrate and CO2 concentration of flue gas in real time. The model validation shows high prediction accuracy, and the potential impact of meteorological parameters on model accuracy is assessed. The results demonstrate that the Transformer model outperforms other models and using near-infrared spectral data as input features improves the prediction accuracy.