期刊
FLUID PHASE EQUILIBRIA
卷 384, 期 -, 页码 95-99出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.fluid.2014.10.032
关键词
Clathrate hydrate; Gas hydrate; Carbon dioxide; Ethane; Hydrate promoters
Equilibrium conditions for clathrate hydrates formed from carbon dioxide or ethane in aqueous solutions of 1,4-dioxane and 1,3-dioxolane were determined experimentally using an isochoric method. Addition of the 1,4-dioxane and 1,3-dioxolane to water shifted the equilibrium conditions of carbon dioxide hydrates to a higher temperature, indicating that they promote carbon dioxide hydrate formation. In contrast, 1,4-dioxane and 1,3-dioxolane inhibited ethane hydrate formation at pressures greater than 0.7 MPa. (C) 2014 Elsevier B.V. All rights reserved.
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