期刊
FARADAY DISCUSSIONS
卷 170, 期 -, 页码 223-233出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4fd00007b
关键词
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资金
- Garmor, Inc.
- AMG renewables, LLC
Mechanochemical approaches to chemical synthesis offer the promise of improved yields, new reaction pathways and greener syntheses. Scaling these syntheses is a crucial step toward realizing a commercially viable process. Although much work has been performed on laboratory-scale investigations little has been done to move these approaches toward industrially relevant scales. Moving reactions from shaker-type mills and planetary-type mills to scalable solutions can present a challenge. We have investigated scalability through discrete element models, thermal monitoring and reactor design. We have found that impact forces and macroscopic mixing are important factors in implementing a truly scalable process. These observations have allowed us to scale reactions from a few grams to several hundred grams and we have successfully implemented scalable solutions for the mechanocatalytic conversion of cellulose to value-added compounds and the synthesis of edge functionalized graphene.
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