期刊
EXPRESS POLYMER LETTERS
卷 8, 期 7, 页码 528-542出版社
BUDAPEST UNIV TECHNOL & ECON
DOI: 10.3144/expresspolymlett.2014.56
关键词
polymer composites; superhydrophobic surface; photo-sensitive; thermal-sensitive; click chemistry
资金
- Research Fund for the Doctoral Program of Higher Education of China [20120161110024]
- National Natural Science Foundation of China [J1210040]
A dual-switchable surface between hydrophobic and superhydrophobic has been fabricated successfully by combining reversible addition-fragmentation chain transfer polymerization (RAFT) polymeric technology and thiol-NCO click chemistry. Well-defined block copolymer, poly(7-(6-(acryloyloxy) hexyloxy) coumarin)-b-poly(N-Isopropylacryl amide), was synthesized by RAFT, and then the block copolymer was grafted onto the surface of SiO2 modified by toluene disocynate (TDI) via thiol-NCO click chemistry. The results of nuclear magnetic resonance (NMR) and Fourier Transform Infrared (FTIR) spectroscopies confirmed that the block copolymer (Number average molecular weight (M-n) = 9400, poly-dispersity index (PDI) = 1.22) has been synthesized successfully. The static contact angle (CA) of the surface prepared by SiO2/P (7-6-AC)-b-PNIPAAm switches from 98 +/- 2 to 137 +/- 2 degrees by adjusting the temperature. Furthermore, the contact angle can also oscillate between 137 +/- 2 and 157 +/- 2 degrees on the irradiation of UV light at 365 and 254 nm, respectively. The dual-switchable surfaces exhibit high stability between hydrophilicity and superhydrophobicity. Therefore, the method provides a new method to fabricate the dual-stimuli-responsive surface with tunable wettability, reversible switching, and also be easily extended to other dual-responsive surfaces. This ability to control the wettability by the adjustment of the temperature and UV light has applications in a broad range of fields.
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