期刊
EXPRESS POLYMER LETTERS
卷 6, 期 10, 页码 814-825出版社
BUDAPEST UNIV TECHNOL & ECON
DOI: 10.3144/expresspolymlett.2012.87
关键词
polymer composites; nanocomposites; material testing; tailor-made polymers; carbon nanotubes
资金
- Finnish Funding Agency for Technology and Innovation (Tekes) [2330/31/06]
- POPROK Graduate School
Carbon nanotubes (CNTs) were melt mixed directly or by using an in situ polymerized masterbatch into a matrix polymer, polystyrene (PS) or poly(methyl methacrylate) (PMMA). The mechanical properties of the composites were mostly determined by the amount of CNTs, and not by the use of directly melt mixed CNTs or the use of the masterbatch. In contrast, the electrical resistivity of the composites was dependent on the manner in which the CNTs were added to the matrix polymer. When there was increased interfacial adhesion between the components, as for PS and the CNTs, the use of directly melt mixed CNTs gave better resistivity results. Without strong interactions between the CNTs and the matrix, as with PMMA and CNTs, the use of a tailored masterbatch had a significant effect on properties of the final composites. The molecular weight and viscosity of masterbatches can be varied and when the PMMA-masterbatch had optimized viscosity with respect to the PMMA matrix, electrical resistivity of the final composites decreased noticeably.
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