期刊
EXPRESS POLYMER LETTERS
卷 2, 期 6, 页码 392-397出版社
BUDAPEST UNIV TECHNOL & ECON
DOI: 10.3144/expresspolymlett.2008.47
关键词
polymer blends and alloys; PP/EPR blends; fracture; damage mechanism; nucleation
The influence of alpha- and beta-nucleating agents on the fracture performance of two different 32 wt% rubber modified isotactic Polypropylene (iPP) reactor blends is discussed as a function of the phase morphology of the investigated systems. Nucleation for systems with a large inter-particle distance was found to have only a limited impact on the temperature at which the ductile-brittle transition occurs, negative for a- nucleated blends, almost negligible for beta-nucleated resins. For blends exhibiting a small inter-particular distance between their ethylene-propylene rubber (EPR) phase, toughness was promoted slightly by a- nucleation and to a large extent by beta-nucleation as compared to a non-nucleated reference. These findings raise the importance of mechanistic synergies between the rubbery phase and the matrix to maximize the fracture resistance of blends.
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