4.7 Article

Poly(hexamethylene terephthalate)-layered silicate nanocomposites

期刊

EUROPEAN POLYMER JOURNAL
卷 46, 期 2, 页码 156-164

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2009.10.018

关键词

Poly(hexamethylene terephthalate); Masterbatch nanocomposites; Aromatic polyesters; Polyester nanocomposites

资金

  1. CICYT (Comision Interministerial de Ciencia y Tecnologia) of Spain [MAT2006-13209-C02-02]
  2. Belgian Science Policy [PAI VI/27]
  3. AGAUR
  4. Beques per a estades de recerca fora de Catalunya

向作者/读者索取更多资源

Nanocomposites of poly(hexamethylene terephthalate) (PHT) and montmorillonite organo-modified with alkylammonium cations bearing two primary hydroxyl functions, i.e., Cloisite (R) 30B (CL30B) were synthesized. Organoclay incorporation was performed either by dispersion in the PHT matrix via melt blending or by in situ ring-opening polymerization of hexamethylene terephthalate cyclic oligomers c(HT). An additional procedure combining the two methods, preparation of a highly enriched inorganic PHT-CL30B nanohybrid masterbatch by in situ ring-opening polymerization and blending of the masterbatch with additional PHT was explored. The obtained nanocomposites contain 3% (w/w) of inorganics and displayed a mixture of intercalated morphology and exfoliated nanolayers as evidenced by X-ray diffraction and transmission electron microscopy. The nanocomposite obtained by the masterbatch technique exhibited a higher degree of exfoliation and displayed slightly higher glass transition temperatures, better mechanical properties and higher flame resistance. The improved results achieved with the masterbatch route are a consequence of the reactions occurring between the nanocomposite constituents allowing for the grafting of PHT chains onto the organoclay surface. (C) 2009 Elsevier Ltd. All rights reserved.

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