期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 26, 页码 8617-8622出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b04677
关键词
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资金
- National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1265652] Funding Source: National Science Foundation
The observation that NHC-boryl radicals abstract cyano groups from various organic nitriles has been parlayed into two complementary transformations. In the main group chemistry aspect, reactions of various NHC-boranes with simple organic dinitriles selectively provide stable NHC-boryl mono- or dinitriles, depending on the nitrile source. In the organic synthesis aspect, reaction of malononitriles and related derivatives with readily available 1,3-dimethylimidazol-2-ylidene borane provides reductively decyanated products in good yields.
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