4.8 Article

Slow-Reduction Synthesis of a Thiolate-Protected One-Dimensional Gold Cluster Showing an Intense Near-Infrared Absorption

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 22, 页码 7027-7030

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AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b03251

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  1. Elements Strategy Initiative for Catalysis & Batteries (ESICB)
  2. Nanotechnology Platform Program of from the Ministry of Education, Culture, Sports, Science, and Technology (MEXT) of Japan
  3. [26248003]
  4. Grants-in-Aid for Scientific Research [26248003, 14J10502] Funding Source: KAKEN

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Slow reduction of AU ions in the presence of 4-(2-mercaptoethyl)benzoic acid (4-MEBA) gave Au-76(4-MEBA)(44) clusters that exhibited a strong (3 x 10(5) M-1 cm(-1)) near-infrared: absorption band at 1340 nm. Powder X-ray diffraction studies indicated that the Au core has a one-dimensional fcc structure that is elongated along the {100} direction.

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