期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 137, 期 9, 页码 3201-3204出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b00216
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资金
- Institute of Materials Research and Engineering (IMRE)
- National University of Singapore
The reaction of 3-sulfolene with arylboronic acids in the presence of a chiral diene-rhodium catalyst under highly basic conditions (10 equiv of KOH),gave high yields of 3-arylsulfolanes with high enantioselectivity, where 3-sulfoleneis in equilibration with 2-sulfolene by base-catalyzed isomerization and the more reactive 2-sulfolene undergoes the rhodium-catalyzed asymmetric arylation.
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