期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2014, 期 9, 页码 1925-1934出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201301716
关键词
Synthetic methods; Asymmetric synthesis; Rearrangement; Amides
资金
- Hawler Medical University, Kurdistan, Iraq
- EPSRC National X-ray Crystallography Service
- EPSRC National Mass Spectrometry Facility (NMSF)
A new and mild method for the production of diasteromerically enriched -aryl carbonyl compounds has been achieved. Although only modest diastereoselectivies are observed, they demonstrate the potential of the method for further optimisation. It also appears that reactions that proceed through a five-membered spirocyclic transition state rearrange, whereas those proceeding through a six-membered transition state do not, but stop at the diaryl ether stage.
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