期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2013, 期 33, 页码 7480-7483出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201301430
关键词
C-H activation; Rhodium; Amination; Azides
资金
- National Basic Research Program of China (973 Program) [2009CB825300]
- National Natural Science Foundation of China [21172006]
- Ph. D. Program Foundation of the Ministry of Education of China [20120001110013]
A novel and efficient Rh-catalyzed intermolecular C-H amination of heteroarylarenes with aryl azides has been developed. This procedure does not require an oxidant, releases N-2 as the only byproduct, and provides an efficient approach to diarylamines with broad functional-group tolerance.
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