期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2013, 期 23, 页码 5106-5110出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201300361
关键词
Synthetic methods; Homogeneous catalysis; Alcohols; Copper; Oxidation
资金
- University Grant Commission (UGC), India under UGC-SAP of the Institute of Chemical Technology (ICT), Matunga
An efficient methodology has been developed for the synthesis of nitriles through an aerobic oxidative reaction of alcohols and ammonium formate with copper as a homogeneous catalyst under a normal air atmosphere and solvent-free conditions. This protocol uses the air as a green oxidant and ammonium formate as the nitrogen source. A wide range of substrates were well tolerated in the reaction that gave water as a byproduct.
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