期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2013, 期 19, 页码 3983-3987出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201300515
关键词
Enantioconvergent reactions; Palladium; Chirality; Allylic compounds; Boranes
资金
- Robert A. Welch Foundation [A-1700]
- National Science Foundation (NSF) [CHE-1150606]
A catalytic enantioconvergent process has been developed for the conversion of racemic allyl indolenin-3-carboxylates into enantiomerically enriched C3-quaternary indolenines. A Pd-catalyzed decarboxylative allylic alkylation reaction was employed for both stereoablation of the racemic allyl indolenin-3-carboxylates and enantioselective formation of the quaternary carbon center.
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