期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2013, 期 15, 页码 3041-3048出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201201696
关键词
Synthetic methods; Heterogeneous catalysis; Copper; Alkynes; Allenes
资金
- National Basic Research Program of China [2009CB825300]
- National Natural Science Foundation of China (NSFC) [21232006]
Relative to our original protocol that uses CuI (0.5 equiv.), paraformaldehyde (2.5 equiv.), and dicyclohexylamine (1.8 equiv.), a facile and efficient protocol for the gram-scale synthesis of functionalized terminal allenes by using CuI (7.5-10 mol-%), paraformaldehyde (1.6 equiv.), and diisopropylamine (1.4 equiv.) has been developed. This method accommodates different functional groups such as hydroxy or carbonyl, and it also performed well in the synthesis of allenylamides and 2,3-butadien-1-ol.
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