期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2013, 期 18, 页码 3910-3918出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201300248
关键词
Sulfur; Selenide; C-H activation; Arenes; Iridium; Copper
资金
- National Science Council, Taiwan [NSC 101-2113-M-005-008-MY3]
- National Chung Hsing University
- Center of Nanoscience and Nanotechnology (NCHU)
A general procedure for the synthesis of aryl thioethers and aryl selenides in one-pot through sequential iridium-catalyzed C-H borylation and copper-promoted C-S and C-Se bond formation is described. Functional groups including chloro, nitro, fluoro, trifluoromethyl, and nitrogen-containing heterocycles were all tolerated under the reaction conditions. Importantly, not only aryl thiols and selenides but also their alkyl analogs were suitable coupling partners, and the products were obtained in good yields with high meta regioselectivity.
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