期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2013, 期 21, 页码 4471-4482出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201201675
关键词
TADDOLs; Chiral pool; H-bonding catalysis; Phase-transfer catalysis; Chiral Lewis bases; Asymmetric catalysis
资金
- Austrian Science Funds (FWF) [P22508-N17]
- Austrian Science Fund (FWF) [P22508] Funding Source: Austrian Science Fund (FWF)
- Austrian Science Fund (FWF) [P 22508] Funding Source: researchfish
Tartaric acid is one of the most prominent naturally occurring chiral compounds. Whereas its application in the production of chiral ligands for metal-catalysed reactions has been exhaustively investigated, its potential to provide new organocatalysts has been less extensively explored. Nevertheless, some impressive results, such as the use of TADDOLs as chiral H-bonding catalysts or of tartrate-derived asymmetric quaternary ammonium salt catalysts, have been reported over the last decade. The goal of this article is to provide a representative overview of the potential and the limitations of tartaric acid or TADDOLs in the creation of new organocatalysts and to highlight some of the most spectacular applications of these catalysts, as well as to summarize case studies in which other classes of chiral backbones were better suited.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据