期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2013, 期 16, 页码 3271-3277出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201300080
关键词
Natural products; Alkaloids; Total synthesis; Nitrogen heterocycles; Aromatization
资金
- National Natural Science Foundation of China (NSFC) [20972048]
- Shanghai Educational Development Foundation [03SG27]
- Ministry of Education and Training, Vietnam
The first total synthesis of eudistomin Y-7 (7) and total syntheses of eudistomins Y-1-Y-6 (1-6) are described. An efficient room-temperature conversion of 1-benzyl-3,4-dihydro-beta-carbolines (11) into 1-benzoyl-beta-carbolines (14) by a one-pot process of tandem benzylic oxidation and aromatization as the key step of these total syntheses was also studied in detail.
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