期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2013, 期 6, 页码 1027-1039出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201201441
关键词
Copper; Silver; Gold; Alkenes; Allenes; Oxygen heterocycles
资金
- Engineering and Physical Sciences Research Council (EPSRC) [EP/G070172/1]
- Fundacion Barric de la Maza
- Xunta de Galicia
- EPSRC [EP/G070172/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/G070172/1] Funding Source: researchfish
The direct addition of O-H bonds to C=C bonds is a very attractive way of synthesising alcohols, ethers and esters, due to the inherent atom- and step-economy of the process. This microreview focuses on the development of group 11 metal catalysts in mediating these transformations. Bronsted acid catalysis has been shown to play a role in some of these processes, and this is highlighted where appropriate. The utility of these methods in organic synthesis is addressed through selected examples.
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