期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2012, 期 19, 页码 3625-3635出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201200205
关键词
Supported catalysts; Heterogeneous catalysis; Green chemistry; Palladium; Carbenes; Sol-gel processes; Cross-coupling; C-C coupling
资金
- Spanish Ministerio de Ciencia e Innovacion (MICINN) [CTQ2009-07881, CTQ2009-08328]
- Consolider Ingenio [CSD2007-00006]
- Generalitat de Catalunya [SGR2009-01441]
- French Centre National de la Recherche Scientifique (CNRS)
Two silylated PdNHC complexes were immobilized on hybrid silicas by sol-gel cocondensation with tetraethyl orthosilicate (TEOS) and performed well as recyclable catalysts towards the Heck, Suzuki, and Sonogashira coupling reactions. Remarkable conversion and recyclability were achieved in the Suzuki reaction with a challenging aryl chloride. No side products and no undesired homocoupling were observed in Suzuki or Heck reactions, which facilitates the final purification step for the cross-coupling products. High turnover numbers and turnover frequencies were found for copper- and phosphane-free Sonogashira reaction between p-bromoacetophenone and phenylacetylene.
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