The New Age of Electrophilic Perfluoro­alk­ylation Reactions

Copper-mediated trifluoromethylation of arylboronic acids by trifluoromethyl sulfonium salts

(2011) Cheng-Pan Zhang et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed trifluoromethylation of aryl boronic acids using a CF3+ reagent

(2011) Jun Xu et al.   CHEMICAL COMMUNICATIONS

Generation of the CF3 radical from trifluoromethylsulfonium triflate and its trifluoromethylation of styrenes

(2011) Cheng-Pan Zhang et al.   CHEMICAL COMMUNICATIONS

Enantioselective Organocatalytic Synthesis of Fluorinated Molecules

(2011) Guillem Valero et al.   CHEMISTRY-A EUROPEAN JOURNAL

N,N-Dimethyl-S-difluoromethyl-S-phenylsulfoximinium tetrafluoroborate: A versatile electrophilic difluoromethylating reagent

(2011) G.K. Surya Prakash et al.   JOURNAL OF FLUORINE CHEMISTRY

Electrophilic Trifluoromethylation ofS-Hydrogen Phosphorothioates

(2011) Nico Santschi et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Trifluoromethylation of Terminal Alkenes through Allylic C–H Bond Activation

(2011) Jun Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed C(sp3)–C(sp3) Bond Formation Using a Hypervalent Iodine Reagent: An Efficient Allylic Trifluoromethylation

(2011) Xi Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of α-CF3-Substituted Carbonyl Compounds with Relative and Absolute Stereocontrol Using Electrophilic CF3-Transfer Reagents

(2011) Václav Matoušek et al.   ORGANIC LETTERS

Cu-Mediated Chemoselective Trifluoromethylation of Benzyl Bromides Using Shelf-Stable Electrophilic Trifluoromethylating Reagents

(2011) Hiroyuki Kawai et al.   ORGANIC LETTERS

Synthesis of CF3-Substituted Sulfoximines from Sulfonimidoyl Fluorides

(2011) Rafal Kowalczyk et al.   ORGANIC LETTERS

Copper-Catalyzed Trifluoromethylation of Aryl and Vinyl Boronic Acids with An Electrophilic Trifluoromethylating Reagent

(2011) Tianfei Liu et al.   ORGANIC LETTERS

Divergent Preparation of Fluoroalkylated Sulfilimine and Sulfilimino Iminium Salts

(2010) Céline Urban et al.   ADVANCED SYNTHESIS & CATALYSIS

Inherent Oxygen Preference in Enolate Monofluoromethylation and a Synthetic Entry to Monofluoromethyl Ethers

(2010) Yoshinori Nomura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

P-Stereogenic Ferrocene-Based (Trifluoromethyl)phosphanes: Synthesis, Structure, Coordination Properties and Catalysis

(2010) Aline Sondenecker et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Fluorine in health care: Organofluorine containing blockbuster drugs

(2010) David O’Hagan   JOURNAL OF FLUORINE CHEMISTRY

Electrophilic trifluoromethylation of arenes and N-heteroarenes using hypervalent iodine reagents

(2010) Matthias S. Wiehn et al.   JOURNAL OF FLUORINE CHEMISTRY

Reactivity of a Hypervalent Iodine Trifluoromethylating Reagent toward THF: Ring Opening and Formation of Trifluoromethyl Ethers

(2010) Serena Fantasia et al.   JOURNAL OF ORGANIC CHEMISTRY

The Productive Merger of Iodonium Salts and Organocatalysis: A Non-photolytic Approach to the Enantioselective α-Trifluoromethylation of Aldehydes

(2010) Anna E. Allen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzedortho-Trifluoromethylation of Arenes Using TFA as a Promoter

(2010) Xisheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidation of a Cyclometalated Pd(II) Dimer with “CF3+”: Formation and Reactivity of a Catalytically Competent Monomeric Pd(IV) Aquo Complex

(2010) Yingda Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrophilic Trifluoromethylation of Primary Phosphines: Synthesis of aP-Bis(trifluoromethyl) Derivative of BINAP

(2010) Nicolas Armanino et al.   ORGANOMETALLICS

New hypervalent iodine reagents for electrophilic trifluoromethylation and their precursors: synthesis, structure, and reactivity

(2010) Katrin Niedermann et al.   TETRAHEDRON

Mechanistical insight into ‘electrophilic’ trifluoromethylation with S-(trifluoromethyl)dibenzothiophenium salts

(2010) Yohan Macé et al.   TETRAHEDRON LETTERS

Direct C2-trifluoromethylation of indole derivatives catalyzed by copper acetate

(2010) Ryo Shimizu et al.   TETRAHEDRON LETTERS

Acid-mediated formation of trifluoromethyl sulfonates from sulfonic acids and a hypervalent iodine trifluoromethylating agent

(2009) Raffael Koller et al.   CHEMICAL COMMUNICATIONS

Selective difluoromethylation and monofluoromethylation reactions

(2009) Jinbo Hu et al.   CHEMICAL COMMUNICATIONS

Fluorine & chirality: how to create a nonracemic stereogenic carbon–fluorine centre?

(2009) Dominique Cahard et al.   CHEMICAL SOCIETY REVIEWS

Benchmark and Solvent-Free Preparation of Sulfonium Salt Based Electrophilic Trifluoromethylating Reagents

(2009) Yohan Macé et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective electrophilic trifluoromethylation of β-keto esters with Umemoto reagents induced by chiral nonracemic guanidines

(2009) Shun Noritake et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

N-Tosyl-S-difluoromethyl-S-phenylsulfoximine: A New Difluoromethylation Reagent for S-, N-, and C-Nucleophiles

(2009) Wei Zhang et al.   ORGANIC LETTERS

Design, synthesis, and structure–activity relationship of novel CCR2 antagonists

(2008) Shankaran Kothandaraman et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Mild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(iii)–CF3 reagents

(2008) Patrick Eisenberger et al.   CHEMICAL COMMUNICATIONS

Update 1 of: Asymmetric Fluorination, Trifluoromethylation, and Perfluoroalkylation Reactions

(2008) Jun-An Ma et al.   CHEMICAL REVIEWS

Synthesis, Structure, and Transport Property of Perfluorinated Oligofluorenes

(2008) Kimitaka Ohkubo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Fluorinated Johnson Reagent for Transfer-Trifluoromethylation to Carbon Nucleophiles

(2008) Shun Noritake et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

ElectrophilicS-Trifluoromethylation of Cysteine Side Chains inα- andβ-Peptides: Isolation of Trifluoro-methylatedSandostatin®(Octreotide) Derivatives

(2008) Stefania Capone et al.   HELVETICA CHIMICA ACTA

The Many Roles for Fluorine in Medicinal Chemistry

(2008) William K. Hagmann   JOURNAL OF MEDICINAL CHEMISTRY

Reactivity of a 10-I-3 Hypervalent Iodine Trifluoromethylation Reagent With Phenols

(2008) Kyrill Stanek et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Electrophilic Monofluoromethylation

(2008) G. K. Surya Prakash et al.   ORGANIC LETTERS

Electrophilic (phenylsulfonyl)difluoromethylation of thiols with a hypervalent iodine(III)–CF2SO2Ph reagent

(2008) Wei Zhang et al.   TETRAHEDRON LETTERS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS

A new method for the synthesis of trifluoromethylating agents—Diaryltrifluoromethylsulfonium salts

(2007) Lev M. Yagupolskii et al.   JOURNAL OF FLUORINE CHEMISTRY