期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2011, 期 12, 页码 2293-2300出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201001438
关键词
Lactones; Hydroxamic acids; Nitrile oxides; Thiohydroximates; Glucosinolates; Carbohydrates; Natural products
资金
- French Embassy in Lithuania
A new method for accessing the thiohydroximate function allows an alternative synthetic pathway to glucosinolates. O-Silylated hydroxamic acids were prepared and were then activated with triflic anhydride to generate transient nitrile oxides to be condensed with ethanethiol. The procedure was further applied to the synthesis of naturally occurring glucosinolates.
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