期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2012, 期 6, 页码 1171-1178出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201101231
关键词
Supramolecular chemistry; Rotaxanes; Macrocycles; Molecular devices
资金
- Deutsche Forschungsgemeinschaft (DFG) [SFB 765]
- Fonds der Chemischen Industrie (FCI)
- Studienstiftung des Deutschen Volkes
Bromo-substituted Hunter/Vogtle-type tetralactam macrocycles (TLMs) represent key intermediates for the attachment of terpyridyl and phenanthroline metal binding sites through cross-coupling reactions. From these monovalent precursors, metal complexes can easily be obtained that present the macrocycles in a multivalent fashion. Depending on the nature of the metal ion, the properties of the complexes can be tuned with respect to valency (e.g., phen-TLM + CuI: divalent, phen-TLM + FeII: trivalent) and lability against TLM ligand exchange (e.g., CuI: slow, but reversible exchange, RuIICl2: kinetically inert).
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