期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2011, 期 14, 页码 2610-2614出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201100129
关键词
Cyclization; Carbocycles; Carbocyclization; Enynes; Allenes; Titanium
资金
- Shanghai Municipal Committee of Science and Technology [08dj1400100-2]
- National Basic Research Program of China (973) [2009CB825300]
- Fundamental Research Funds for the Central Universities
- National Natural Science Foundation of China [21072206, 20472096, 20872162, 20672127, 20821002, 20732008]
1,6-Enynes can be transformed into 3-azabicyclo[3.1.0]hexanes and functionalized allenes in moderate to good yields along with moderate to high diastereoselectivities by controlling the reaction temperature in the presence of titanium(IV) chloride. A plausible mechanism is proposed.
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