期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2010, 期 26, 页码 5090-5099出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201000671
关键词
Cross-coupling; Homogeneous catalysis; Nanoparticles; Palladium; Suzuki reaction
资金
- Ministerio de Educacion y Ciencia (MEC)
- Ministerio de Ciencia e Innovacion (MICINN) of Spain [CTQ2007-65720, CTQ2009-07881/BQU]
- Ramon y Cajal
- Consolider Ingenio 2010 [CSD2007-00006]
- Generalitat de Catalunya [SGR2009-01441]
A new PEG-tagged material, which was prepared by a threefold copper-catalyzed [3+2] cycloaddition (click chemistry), was found to act as an efficient stabilizer for palladium nanoparticles. The newly formed material proved to be active as a recyclable catalyst in Suzuki coupling; the presence of polyether chains allowed for the catalytic runs to be conducted in aqueous media.
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