期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2011, 期 2, 页码 234-237出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201001423
关键词
Benzimidazoles; Nitrogen heterocycles; Palladium; Homogeneous catalysis; Regioselectivity
资金
- European community
Unsymmetric, N-substituted benzimidazoles and imidazopyridines can be prepared directly from 2-halonitroarenes and amides through Pd(TFA)(2)/(R)-BINAP-catalyzed cross-coupling and subsequent reductive aminocyclization. This sequence can be conducted by a one-pot procedure. The method is versatile and allows the straightforward, regioselective preparation of these important nitrogen heterocycles.
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