期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2010, 期 34, 页码 6582-6587出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201001067
关键词
Domino reactions; Electrocyclic reactions; Microwave chemistry; Nitrogen heterocycles; Nicotinic acid
资金
- Spanish Ministerio de Ciencia e Innovacion (MICINN)
- European Regional Development Fund [CTQ2008-06806-C02-02]
- Spanish Ministerio de Sanidad y Consumo, Instituto de Salud Carlos III (MSC ISCIII) [RE-TICS RD06/0020/1046]
- Fundacion Canaria de Investigacion y Salud (FUNCIS) [REDESFAC PI01/06]
- Fundacion Instituto Canario de Investigacion del Cancer [FICI-G.I.N808/2007]
- Spanish Ministerio de Educacion y Ciencia (MEC)
The microwave-assisted diversity-oriented domino synthesis of functionalized alkyl nicotinates from propargyl vinyl ethers is described. The domino manifold comprises a complex network of reactions involving at least five distinct chemical steps. The obtained alkyl nicotinates incorporate two diversity points at the ring and one ester functionality as convenient handles for further elaboration.
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