期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2009, 期 8, 页码 1256-1262出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200801068
关键词
Natural products; NMR spectroscopy; Structure elucidation; Peptides
资金
- Kompetenzzentrum der integrierten Naturstoff-Forschung
Omphalotins E-I, oxidatively modified cyclic dodecapeptides, were isolated from mycelial extracts of the basidiomycete Omphalotus olearius, and their structures were determined by NMR spectroscopic and MS methods. Four of the five omphalotins contained an unprecedented N-hydroxylated tricyclic tryptophan derivative. All compounds exhibited strong and selective nematicidal activity against the plant pathogen Meloidogyne incognita with LD90 values between 2 and 5 mu gmL(-1). Cytotoxic activities were not detected up to 50 mu gmL(-1). ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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