期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2009, 期 11, 页码 1781-1795出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200801277
关键词
Magnesium; Zinc; Amides; Metalation; Copper; Homogeneous catalysis
资金
- Fonds der Chemischen Industrie (FCI)
- Deutsche Forschungsgemeinschaft (DFG)
- ERC (European Research Council)
New mixed Li/Mg and Li/Mg/Zn amides have been synthesized starting from readily prepared secondary amines. They allow a highly chemoselective directed magnesiation or zincation of various polyfunctional aromatics and heteroaromatics. The kinetic basicity, solubility and stability of these new bases have been compared with those of the corresponding 2,2,6,6-tetramethylpiperamide-derived bases. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据
分享论文
