期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2008, 期 15, 页码 2544-2550出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200800005
关键词
carbon; nanotubes; functionalization; lithium; nucleophilic addition; reactivity
The synthesis and characterization of sidewall-functionalized SWNT derivatives (nPrNH)(n)-SWNTs containing n-propylamine addends is reported. The nucleophilic addition of in situ generated lithium n-propylamide to the sidewall of SWNTs and the subsequent reoxidation of charged intermediates of the type (nPrNH)(n)-SWNTn- leads to carbon nanotube derivatives with covalently attached amino groups. Based on the reaction sequence, a homogeneous dispersion of the carbon nanotube material is achieved as a result of the electrostatic repulsion of negatively charged intermediates. The solubility of the resulting propylamine-functionalized (nPrNH)(n)-SWNT material in organic solvents is drastically increased. The functionalized tubes were characterized in detail by Raman spectroscopy, thermogravimetric analysis (TGA/MS), X-ray photoelectron spectroscopy (XPS) and UV/Vis/NIR spectroscopy. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).
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