Review
Chemistry, Physical
Mohamad Razlan Md Radzi, M. Devendran Manogaran, Mohd Hizami Mohd Yusoff, Zulqarnain, Mohd Razealy Anuar, Noor Fazliani Shoparwe, Mohd Fikri Ab Rahman
Summary: The study explores the possibility of producing 1,2-propanediol and 1,3-propanediol through aqueous phase reforming, which offers a low temperature requirement and high H-2 yields. Various catalyst combinations have been identified for optimal yields, with a Cu-based catalyst and a noble metal-dopant-support combination being key factors for 1,2-propanediol and 1,3-propanediol production respectively. The findings show potential for high yields of both products, especially for 1,2-propanediol.
Article
Chemistry, Physical
Mukesh Kumar Poddar, Ankit Pandey, Mukund Kumar Jha, Suresh Chandra Andola, Syed Saif Ali, Sonu Bhandari, Govind Kumar Sahani, Rajaram Bal
Summary: This study investigated the effect of Cu and Ni on the hydrogenolysis of glycerol to produce 1, 2-Propanediol, finding that Cu nanoparticles are critical for the selective production of the desired product. The mesoporous alumina support played a crucial role in enhancing the performance of Cu and Ni oxide particles, with both acid and metal functions contributing to increasing selectivity for 1, 2-Propanediol.
MOLECULAR CATALYSIS
(2021)
Article
Chemistry, Physical
Ain Syuhada, Mariam Ameen, Mohammad Tazli Azizan, Aqsha Aqsha, Mohd Hizami Mohd Yusoff, Anita Ramli, Mohamad Sahban Alnarabiji, Farooq Sher
Summary: This study investigated the production of 1,3-Propanediol using Ni-Ca/CeO2 catalysts synthesized by sonochemical and wet impregnation methods. Sonochemically prepared catalysts showed better surface characteristics. The Ni/CeO2 catalyst demonstrated the highest activity and selectivity for 1,3-Propanediol production.
MOLECULAR CATALYSIS
(2021)
Article
Chemistry, Applied
Aracelis J. Pamphile-Adrian, Fabio B. Passos, Pedro P. Florez-Rodriguez
Summary: A systematic study was conducted to determine the maximum amount of nickel incorporated into the gamma-Al2O3 structure to form NiAl2O4. The behavior of this catalyst precursor for glycerol hydrogenolysis and cyclohexane conversion was investigated. Various characterization techniques were used to study the prepared catalysts with different nickel content. The results showed that Ni could be reversibly inserted into the gamma-Al2O3 structure, and the maximum amount of Ni incorporated into NiAl2O4 was approximately 20 wt%Ni. Different forms of Ni0 particles were observed depending on the Ni content, and their nature affected the catalytic activity. The formation of gridshell structures was found to be a determining factor for the catalytic activity in liquid-phase reactions.
Review
Chemistry, Multidisciplinary
Xi Liu, Bin Yin, Wenxiang Zhang, Xiao Yu, Yiyao Du, Siming Zhao, Guangyu Zhang, Mengyuan Liu, Hao Yan, Manuela Abbotsi-Dogbey, Saleem T. Al-Absi, Sayan Yeredil, Chaohe Yang, Jian Shen, Wenjuan Yan, Xin Jin
Summary: This review critically revises the transfer hydrogenolysis of glycerol on metallic catalysts, focusing on surface reaction mechanism and catalyst design. Detailed discussion on reaction pathways for H-2 generation and insights into structure-performance relation for future catalyst manufacture and process development are provided.
Article
Chemistry, Multidisciplinary
Yang Zeng, Lan Jiang, Xiaoxin Zhang, Songhai Xie, Yan Pei, Gongbing Zhou, Weiming Hua, Minghua Qiao, Zhen-Hua Li, Baoning Zong
Summary: This study investigates the impact of TiO2 support polymorphs on Pt-WOx catalysts for glycerol hydrogenolysis, revealing that the crystal structures differences affect the size of Pt nanoparticles and the dispersion and location of WOx species, thereby influencing the catalytic performance.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2022)
Review
Multidisciplinary Sciences
Jude A. Okolie
Summary: This study reviews different catalyst for glycerol hydrogenorisis, the reaction mechanism, and process challenges, and presents in detail previous studies related to the economic and environmental assessment of propylene glycol production.
Article
Chemistry, Physical
Shijie Cheng, Yiqiu Fan, Xiaoxin Zhang, Yang Zeng, Songhai Xie, Yan Pei, Gaofeng Zeng, Minghua Qiao, Baoning Zong
Summary: By varying the mass ratio of the swelling agent and the template during the synthesis, a series of tungsten-doped Pt/W-MCFs catalysts were prepared, with Pt/W-1.5MCFs showing the highest 1,3-propanediol selectivity and activity. The synergy between Pt nanoparticles and single-sited tetrahedral (WO4)-O-V species at the metal-oxide interface is proposed to be responsible for the differences in catalytic performances among the Pt/W-MCFs catalysts.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Engineering, Environmental
Naveen Kumar Mishra, Praveen Kumar, Vimal Chandra Srivastava, Urska Lavrencic Stangar
Summary: The study highlighted the importance of catalyst basicity in catalytic transfer hydrogenation, with copper playing a significant role in the cleavage of glycerol. A proposed reaction mechanism involved ethanol hydrogenation at copper sites and the formation of intermediates at the basic sites of the catalysts.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Chemistry, Multidisciplinary
Shizhuo Wang, Jikang Jiang, Minyan Gu, Feng Gao, Zheng Shen
Summary: An efficient Pt/deAl-beta@Mg(OH)2 catalyst was designed and used to produce 1,2-propanediol (1,2-PDO) from sucrose. The optimized conditions resulted in a yield of 33.5% 1,2-PDO. The modified beta zeolite with a core-shell structure showed good stability, maintaining a yield of over 30% after three cycles of reuse. Dealuminated zeolite increased the acid sites, while Pt loading enhanced the distribution of acid sites and improved the shape selectivity of the catalyst. The introduction of alkali inhibited side reactions and increased product yield. These modifications promoted the production of 1,2-PDO, providing a theoretical basis and reference for biomass conversion technology in practical production.
Article
Chemistry, Physical
Victor G. S. Mendonca, Isabelle C. Freitas, Robinson L. Manfro, Mariana M. V. M. Souza
Summary: Cu-Ni / xMgO-Al2O3 catalysts were used for the hydrogenolysis of glycerol to produce 1,2-propanediol without the addition of external hydrogen. The addition of MgO to alumina improved the yield of 1,2-propanediol. The rate limiting step for MgO-Al2O3 catalysts is the hydrogenation of acetol, while Cu-Ni / MgO catalysts follow a basic route.
APPLIED CATALYSIS A-GENERAL
(2022)
Review
Chemistry, Applied
Alisson Dias da Silva Ruy, Rita Maria de Brito Alves, Thiago Lewis Reis Hewer, Danilo de Aguiar Pontes, Leonardo Sena Gomes Teixeira, Luiz Antonio Magalhaes Pontes
Summary: 1,3-Propanediol (1,3-PDO) is obtained from renewable and environmentally friendly glycerol, with high cost genetically modified microorganisms currently used in industrial production. Studies have shown that platinum, iridium, and copper are the most promising metals, with Brønsted sites responsible for higher selectivity and Lewis sites influencing reaction rates.
Article
Chemistry, Applied
Harisekhar Mitta, Nagaraju Devunuri, Jyothi Sunkari, Suresh Mutyala, Putrakumar Balla, Vijayanand Perupogu
Summary: The study reported a series of copper-loaded magnesium-aluminum-gallium oxide catalysts prepared by wet impregnation method, where gallium was found to have significant effects on the final catalysts. The catalytic activity of copper was identified as crucial for glycerol hydrogenolysis, with lower copper loading showing higher selectivity to 1,2-propanediol due to highly dispersed particles and sufficient amount of basic and acido-basic sites. The optimized reaction conditions for glycerol conversion were systematically investigated, including copper loading, Mg/Al/Ga ratios, reaction temperature, hydrogen flow rate, glycerol concentration, and weight hourly space velocity, further establishing stability, reusability, and structure-activity correlation of the catalyst.
Article
Chemistry, Multidisciplinary
Honghui Gong, Xiuge Zhao, Xiyu Li, Manyu Chen, Yuan Ma, Jian Fang, Xinjia Wei, Qingpo Peng, Zhenshan Hou
Summary: Selective hydrogenolysis of biomass-derived glycerol into 1,2-propanediol using hydrotalcite-derived catalysts demonstrated high activity and stability, and showed potential for application in selective hydrogenolysis of other sugar polyols. The formation of mixed metal oxides CaO-CoAl2O4 was crucial for enhancing catalytic performance and preventing leaching of active sites and metal species, leading to remarkable catalytic stability under aqueous phase reaction conditions.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Chemistry, Multidisciplinary
Jinghu Chen, Qineng Xia, Yong Guo, Yangang Wang, Xi Li, Mingming Wang, Jieshan Qiu, Yanqin Wang, Maria Veronica Sofianos, Shaomin Liu
Summary: A Pt-loaded Nb-W composite oxide catalyst is developed for the selective hydrogenolysis of glycerol to 1,3-propanediol. This catalyst demonstrates precise activation and cleavage of secondary C-O (C(2)-O) bonds, resulting in high yield of catalytic conversion of glycerol.
Article
Chemistry, Physical
Jawaher Mosrati, Hanan Atia, Reinhard Eckelt, Thanh Huyen Vuong, Jabor Rabeah, Mourad Mhamdi, Udo Armbruster
Summary: NOx reduction using NH3-SCR technology is an efficient method for reducing nitrogen oxide emissions, and the Mo5/Ce40/Ti100 (SG) catalyst supported on ceria-titania shows excellent performance at low temperatures, achieving high NOx conversion rates and N-2 selectivity.
JOURNAL OF CATALYSIS
(2021)
Article
Chemistry, Applied
Nils Ortner, Henrik Lund, Udo Armbruster, Sebastian Wohlrab, Evgenii Kondratenko
Summary: The effects of metal oxide promoter and InOx on catalyst activity and product selectivity in the CO2 hydrogenation to methanol reaction were investigated. The promoters influenced the rates of direct CO2 conversion and methanol decomposition by affecting the dispersion of CuOx and the strength of basic sites for CO2 adsorption.
Article
Engineering, Chemical
Jon Solar, Blanca M. Caballero, Alexander Lopez-Urionabarrenechea, Esther Acha, Pedro L. Arias
Summary: The pyrolysis of woody biomass waste can produce gas, solid, and liquid products, with different temperatures affecting the product yields and composition. Higher temperatures lead to increased gas yield, decreased solid and liquid yields, and changes in the composition of charcoal obtained.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2021)
Article
Chemistry, Physical
B. Torres-Olea, C. Garcia-Sancho, J. A. Cecilia, M. Oregui-Bengoechea, P. L. Arias, R. Moreno-Tost, P. Maireles-Torres
Summary: Nb-Zr oxides were evaluated for glucose dehydration to produce 5-hydroxymethylfurfural. The study showed a linear relationship between the amount of acid sites and niobium content. Nb2O5 demonstrated the highest acid concentration and surface area, with both Bronsted and Lewis acid sites, while Zr-containing catalysts mostly exhibited Lewis acid sites. The combination of CaCl2 and Zr-containing catalysts resulted in direct formation of HMF without fructose, in contrast to Nb2O5 which possesses both types of acid sites. A HMF yield of 44% was achieved with Nb3Zr7 as acid catalyst and CaCl2 after 90 minutes at 175°C, with the catalysts being reusable for at least 3 runs without pretreatment.
MOLECULAR CATALYSIS
(2021)
Article
Thermodynamics
Nerea Viar, Jesus M. Requies, Ion Agirre, Aitziber Iriondo, Cristina Garcia-Sancho, Pedro L. Arias
Summary: In this study, catalysts supported on biomass-derived carbon were used for the hydrogenolysis of HMF to produce DMF and DMTHF in a continuous flow reactor. The carbon-supported catalysts showed good activity and selectivity, outperforming commercial carbon-supported catalysts in terms of selectivity and stability.
Article
Energy & Fuels
Quan Luu Manh Ha, Hanan Atia, Carsten Kreyenschulte, Henrik Lund, Stephan Bartling, Grzegorz Lisak, Sebastian Wohlrab, Udo Armbruster
Summary: This study achieved efficient reforming of biogas using low Ni loading catalysts modified with Gd, Sc, or La. Sc and Gd modifications showed enhanced stability and resistance to coking in DRM reactions with methane-rich gases. Gd-modified catalysts demonstrated minimal increase in coke deposition even after extended operation time.
Review
Chemistry, Physical
Selina Niess, Udo Armbruster, Sebastian Dietrich, Marco Klemm
Summary: Direct biogas methanation faces challenges regarding the influence of high methane content on the reaction and overall efficiency, as well as improving the resistance of catalysts to sulfur-containing compounds. Materials with two active metals and binary oxide support seem to offer technically applicable solutions for these challenges.
Article
Chemistry, Physical
A. Barranca, I Gandarias, P. L. Arias, I Agirrezabal-Telleria
Summary: This study provides new evidence for the one-pot production of 1,5-pentanediol from sustainable sources. The researchers found that by studying the catalysts and reaction conditions, it is possible to directly produce 1,5-pentanediol from furfural at lower temperatures with high productivity. The presence of Co2+ sites in the catalysts showed significant differences compared to other bivalent metals, possibly due to differences in the adsorption positions of reaction intermediates.
Article
Energy & Fuels
Daniel Bielsa, Mikel Oregui, Pedro L. Arias
Summary: This study investigated an established granulation technique using Si-doped manganese oxide as the active material to determine critical parameters for achieving the best chemical and mechanical stability of the granules. The positive effect of decreasing the bath temperature on increasing the volumetric energy density of the granules was identified.
Article
Green & Sustainable Science & Technology
Jorge Blanco, Maria Linares, Manuel Lopez Granados, Ion Agirre, Inaki Gandarias, Pedro Luis Arias, Jose Iglesias, Jovita Moreno, Alicia Garcia
Summary: This study compares the production of maleic anhydride from different feedstock using life cycle analysis and exergy analysis. The results show that the gas phase oxidation of furfural is competitive with petrochemical technologies, while the aqueous phase process is not viable due to energy and environmental concerns. The environmental footprint of the starting raw material is the major drawback for the new furfural-to-maleic anhydride production processes. The use of environmentally friendly furfural production technologies at the commercial scale can improve the environmental performance of gas phase maleic anhydride production.
ADVANCED SUSTAINABLE SYSTEMS
(2022)
Article
Energy & Fuels
Kristian Melin, Jan Ole Struven, Patrick Eidam, Jorn Appelt, Christin Hummel, Udo Armbruster, Yann Chapelliere, Claude Mirodatos, Yves Schuurman, Anja Oasmaa
Summary: A new route for upgrading black liquor from the kraft process to hybrid gasoline is presented. The process involves hydrothermal liquefaction, removal of alkaline metal salts, hydro-deoxygenation, and coprocessing with vacuum gas oil. High deoxygenation is beneficial for cracking the refined crude oil into gasoline fractions. By limiting the percentage of added pretreated biocrude, high naphtha yields can be maintained.
Article
Chemistry, Physical
Francesco Torre, Teresa Aguilar Sanchez, Stefania Doppiu, Mikel Oregui Bengoechea, Pedro Luis Arias Ergueta, Elena Palomo del Barrio
Summary: This study investigates the effect of atomic substitution on the MnFe2O4-Na2CO3 thermochemical cycle for H-2 production. It is found that Na2CO3 substitution for Li2CO3 decreases the decarbonation onset temperature but does not improve the reversibility. Among the substitutions of Mn with Ca, Ni, and Zn, the 5% Zn mixture exhibits the best reversibility and stable H-2 production.
MATERIALS TODAY ENERGY
(2022)
Article
Chemistry, Multidisciplinary
Alberto Barranca, Iker Agirrezabal-Telleria, Marcos Rellan-Pineiro, Manuel A. Ortuno, Inaki Gandarias
Summary: The selective hydrogenolysis of C-OH bond without the hydrogenation of the furan ring is essential in converting biomass-derived platform chemicals. By adjusting the concentration of HCl during catalyst synthesis, the amount of surface chlorine can be fine-tuned, promoting the formation of 2-methylfuran and inhibiting undesired furan ring hydrogenation. Under optimized conditions, a yield of 94% 2-methylfuran and a productivity of approximately 18 mol(2MF) kg(cat)(-1) h(-1) were achieved.
REACTION CHEMISTRY & ENGINEERING
(2023)
Review
Polymer Science
Patricia Ares-Elejoste, Ruben Seoane-Rivero, Inaki Gandarias, Aitziber Iturmendi, Koldo Gondra
Summary: The concerns over the environmental impact of thermoset composites and new legislation have driven the scientific sector to search for sustainable alternatives. Sustainable reinforcements have been widely used to manufacture more sustainable composites, but new alternatives such as bio-based thermosetting resins and recyclable systems have emerged. This review explores these new systems as well as sustainable reinforcements and discusses the biocomposites market and its impact. While significant improvements have been made, further research into alternative solutions is necessary.