期刊
EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY
卷 110, 期 9, 页码 846-852出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejlt.200800024
关键词
Acyloin condensation; Castor oil; Renewable; Tyromycin A; Undecylenic acid
A key intermediate for the synthesis of Tyromycin A, a C-20 tetrachlorodicarboxylic acid, was produced in six steps starting with the dimerization of methyl 10-undecenoate which was obtained from a renewable resource, e.g. castor oil. The acyloin condensation product was then oxidized, transformed to the diene, followed by ozonization, chlorination and finally oxidation to the corresponding tetrachlorodicarboxylic acid.
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