Polyoxometalate Multi-Electron-Transfer Catalytic Systems for Water Splitting

Cobalt porphyrins as homogeneous catalysts for water oxidation

(2013) Takashi Nakazono et al.   CHEMICAL COMMUNICATIONS

Gyroidal metal–organic frameworks by solvothermal subcomponent self-assembly

(2013) Yuan Wu et al.   CHEMICAL COMMUNICATIONS

Shining light on integrity of a tetracobalt-polyoxometalate water oxidation catalyst by X-ray spectroscopy before and after catalysis

(2013) Rafael Schiwon et al.   CHEMICAL COMMUNICATIONS

Water oxidation catalysts based on abundant 1st row transition metals

(2013) Archana Singh et al.   COORDINATION CHEMISTRY REVIEWS

Graphene-supported [{Ru4O4(OH)2(H2O)4}(γ-SiW10O36)2]10− for highly efficient electrocatalytic water oxidation

(2013) Si-Xuan Guo et al.   Energy & Environmental Science

K7[CoIIICoII(H2O)W11O39]: a molecular mixed-valence Keggin polyoxometalate catalyst of high stability and efficiency for visible light-driven water oxidation

(2013) Fangyuan Song et al.   Energy & Environmental Science

Artificial photosynthesis as a frontier technology for energy sustainability

(2013) Thomas Faunce et al.   Energy & Environmental Science

Charge photo-accumulation and photocatalytic hydrogen evolution under visible light at an iridium(iii)-photosensitized polyoxotungstate

(2013) Benjamin Matt et al.   Energy & Environmental Science

Synthesis, Structures, and Photochemistry of Tricarbonyl Metal Polyoxoanion Complexes, [X2W20O70{M(CO)3}2]12– (X = Sb, Bi and M = Re, Mn)

(2013) Chongchao Zhao et al.   INORGANIC CHEMISTRY

Cobalt Polyoxometalates as Heterogeneous Water Oxidation Catalysts

(2013) Joaquín Soriano-López et al.   INORGANIC CHEMISTRY

Voltammetric Determination of the Reversible Potentials for [{Ru4O4(OH)2(H2O)4}(γ-SiW10O36)2]10– over the pH Range of 2–12: Electrolyte Dependence and Implications for Water Oxidation Catalysis

(2013) Yuping Liu et al.   INORGANIC CHEMISTRY

An Inorganic Chromophore Based on a Molecular Oxide Supported Metal Carbonyl Cluster: [P2W17O61{Re(CO)3}3{ORb(H2O)}(μ3-OH)]9–

(2013) Chongchao Zhao et al.   INORGANIC CHEMISTRY

Water Oxidation with Mononuclear Ruthenium(II) Polypyridine Complexes Involving a Direct RuIV═O Pathway in Neutral and Alkaline Media

(2013) Yosra M. Badiei et al.   INORGANIC CHEMISTRY

Visible light-driven water oxidation catalyzed by mononuclear ruthenium complexes

(2013) Lei Wang et al.   JOURNAL OF CATALYSIS

Visible-light-driven hydrogen evolution from water using a noble-metal-free polyoxometalate catalyst

(2013) Hongjin Lv et al.   JOURNAL OF CATALYSIS

Visible Light Driven Water Splitting in a Molecular Device with Unprecedentedly High Photocurrent Density

(2013) Yan Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stabilization of a Ruthenium(II) Polypyridyl Dye on Nanocrystalline TiO2 by an Electropolymerized Overlayer

(2013) Alexander M. Lapides et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic Water Oxidation with a Copper(II) Polypeptide Complex

(2013) Ming-Tian Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Biomimetic Copper Water Oxidation Catalyst with Low Overpotential

(2013) Teng Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Differentiating Homogeneous and Heterogeneous Water Oxidation Catalysis: Confirmation that [Co4(H2O)2(α-PW9O34)2]10– Is a Molecular Water Oxidation Catalyst

(2013) James W. Vickers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fast and Persistent Electrocatalytic Water Oxidation by Co–Fe Prussian Blue Coordination Polymers

(2013) Sara Pintado et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enabling light-driven water oxidation via a low-energy RuIVO intermediate

(2013) Anna Lewandowska-Andralojc et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Water oxidation surface mechanisms replicated by a totally inorganic tetraruthenium-oxo molecular complex

(2013) S. Piccinin et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Water Oxidation Catalysis Beginning with Co4(H2O)2(PW9O34)210– When Driven by the Chemical Oxidant Ruthenium(III)tris(2,2′-bipyridine): Stoichiometry, Kinetic, and Mechanistic Studies en Route to Identifying the True Catalyst

(2013) Jordan J. Stracke et al.   ACS Catalysis

Water Oxidation Catalysis Beginning with 2.5 μM [Co4(H2O)2(PW9O34)2]10–: Investigation of the True Electrochemically Driven Catalyst at ≥600 mV Overpotential at a Glassy Carbon Electrode

(2013) Jordan J. Stracke et al.   ACS Catalysis

Photocatalytic water oxidation with cobalt-containing tungstobismutates: tuning the metal core

(2013) Fabio Evangelisti et al.   Catalysis Science & Technology

Bis(4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine)ruthenium(ii) complexes and their N-alkylated derivatives in catalytic light-driven water oxidation

(2013) Hongjin Lv et al.   RSC Advances

The Artificial Leaf

(2012) Daniel G. Nocera   ACCOUNTS OF CHEMICAL RESEARCH

Knitting the Catalytic Pattern of Artificial Photosynthesis to a Hybrid Graphene Nanotexture

(2012) Mildred Quintana et al.   ACS Nano

Preparation of NiFe2O4 nanoparticles and its visible-light-driven photoactivity for hydrogen production

(2012) Tianyou Peng et al.   CATALYSIS COMMUNICATIONS

Is [Co4(H2O)2(α-PW9O34)2]10− a genuine molecular catalyst in photochemical water oxidation? Answers from time-resolved hole scavenging experiments

(2012) Mirco Natali et al.   CHEMICAL COMMUNICATIONS

Proton-Coupled Electron Transfer

(2012) David R. Weinberg et al.   CHEMICAL REVIEWS

Structure, properties and reactivity of polyoxometalates: a theoretical perspective

(2012) Xavier López et al.   CHEMICAL SOCIETY REVIEWS

Polyoxometalate water oxidation catalysts and the production of green fuel

(2012) Hongjin Lv et al.   CHEMICAL SOCIETY REVIEWS

From serendipity to design of polyoxometalates at the nanoscale, aesthetic beauty and applications

(2012) Leroy Cronin et al.   CHEMICAL SOCIETY REVIEWS

Solar fuels generation and molecular systems: is it homogeneous or heterogeneous catalysis?

(2012) Vincent Artero et al.   CHEMICAL SOCIETY REVIEWS

Tetrametallic molecular catalysts for photochemical water oxidation

(2012) Andrea Sartorel et al.   CHEMICAL SOCIETY REVIEWS

Powering the future of molecular artificial photosynthesis with light-harvesting metallosupramolecular dye assemblies

(2012) Peter D. Frischmann et al.   CHEMICAL SOCIETY REVIEWS

Polyoxometalates Immobilized in Ordered Mesoporous Carbon Nitride as Highly Efficient Water Oxidation Catalysts

(2012) Jian Wu et al.   ChemSusChem

Molecular water oxidation catalysts based on transition metals and their decomposition pathways

(2012) Bart Limburg et al.   COORDINATION CHEMISTRY REVIEWS

A nickel containing polyoxometalate water oxidation catalyst

(2012) Guibo Zhu et al.   DALTON TRANSACTIONS

Effects of aqueous buffers on electrocatalytic water oxidation with an iridium oxide material electrodeposited in thin layers from an organometallic precursor

(2012) Maxwell N. Kushner-Lenhoff et al.   DALTON TRANSACTIONS

Catalytic water oxidation at single metal sites

(2012) Rui Cao et al.   Energy & Environmental Science

Catalysts made of earth-abundant elements (Co, Ni, Fe) for water splitting: Recent progress and future challenges

(2012) Pingwu Du et al.   Energy & Environmental Science

Water-soluble mononuclear cobalt complexes with organic ligands acting as precatalysts for efficient photocatalytic water oxidation

(2012) Dachao Hong et al.   Energy & Environmental Science

A Hexanuclear Cobalt(II) Cluster Incorporated in a Banana-Shaped Tungstovanadate: [(Co(OH2)Co2VW9O34)2(VW6O26)]17-

(2012) Hongjin Lv et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis and characterization of open and sandwich-type polyoxometalates reveals visible-light-driven water oxidation via POM-photosensitizer complexes

(2012) Pierre-Emmanuel Car et al.   GREEN CHEMISTRY

Spectroscopic Studies of Light-driven Water Oxidation Catalyzed by Polyoxometalates

(2012) Zhuangqun Huang et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Photoinduced Water Oxidation by a Tetraruthenium Polyoxometalate Catalyst: Ion-pairing and Primary Processes with Ru(bpy)32+ Photosensitizer

(2012) Mirco Natali et al.   INORGANIC CHEMISTRY

Water Oxidation Catalysis: Influence of Anionic Ligands upon the Redox Properties and Catalytic Performance of Mononuclear Ruthenium Complexes

(2012) Lianpeng Tong et al.   INORGANIC CHEMISTRY

Identification of a Nonanuclear {CoII9} Polyoxometalate Cluster as a Homogeneous Catalyst for Water Oxidation

(2012) Sara Goberna-Ferrón et al.   INORGANIC CHEMISTRY

Detailed Electrochemical Studies of the Tetraruthenium Polyoxometalate Water Oxidation Catalyst in Acidic Media: Identification of an Extended Oxidation Series using Fourier Transformed Alternating Current Voltammetry

(2012) Chong-Yong Lee et al.   INORGANIC CHEMISTRY

Electron Transfer Dynamics in Semiconductor–Chromophore–Polyoxometalate Catalyst Photoanodes

(2012) Xu Xiang et al.   Journal of Physical Chemistry C

Near Unity Quantum Yield of Light-Driven Redox Mediator Reduction and Efficient H2 Generation Using Colloidal Nanorod Heterostructures

(2012) Haiming Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Self-Assembly and Photocatalytic Properties of Polyoxoniobates: {Nb24O72}, {Nb32O96}, and {K12Nb96O288} Clusters

(2012) Peng Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II

(2012) Lele Duan et al.   Nature Chemistry

A soluble copper–bipyridine water-oxidation electrocatalyst

(2012) Shoshanna M. Barnett et al.   Nature Chemistry

Highly efficient and robust molecular ruthenium catalysts for water oxidation

(2012) L. Duan et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Robust Photogeneration of H2 in Water Using Semiconductor Nanocrystals and a Nickel Catalyst

(2012) Z. Han et al.   SCIENCE

Tunable single-site ruthenium catalysts for efficient water oxidation

(2011) Lucile Bernet et al.   CHEMICAL COMMUNICATIONS

A novel sandwich-type polyoxometalate compound with visible-light photocatalytic H2 evolution activity

(2011) Zhenyu Zhang et al.   CHEMICAL COMMUNICATIONS

Visible light-induced wateroxidation catalyzed by molybdenum-based polyoxometalates with mono- and dicobalt(iii) cores as oxygen-evolving centers

(2011) Saya Tanaka et al.   CHEMICAL COMMUNICATIONS

Rates of Water Exchange for Two Cobalt(II) Heteropolyoxotungstate Compounds in Aqueous Solution

(2011) C. André Ohlin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cover Picture: Chemical, Electrochemical, and Photochemical Catalytic Oxidation of Water to Dioxygen with Mononuclear Ruthenium Complexes (ChemSusChem 2/2011)

(2011) Stephan Roeser et al.   ChemSusChem

The effect of peripheral bipyridine ligands on the photocatalytic hydrogen production activity of Ru/Pd catalysts

(2011) Gurmeet Singh Bindra et al.   DALTON TRANSACTIONS

Wateroxidation catalyzed by a new tetracobalt-substituted polyoxometalate complex: [{Co4(μ-OH)(H2O)3}(Si2W19O70)]11−

(2011) Guibo Zhu et al.   DALTON TRANSACTIONS

A visible light water-splitting cell with a photoanode formed by codeposition of a high-potential porphyrin and an iridium water-oxidation catalyst

(2011) Gary F. Moore et al.   Energy & Environmental Science

Water Exchange Reactivity and Stability of Cobalt Polyoxometalates under Catalytically Relevant pH Conditions: Insight into Water Oxidation Catalysis

(2011) Dominik Lieb et al.   INORGANIC CHEMISTRY

Polyoxometalates in the Design of Effective and Tunable Water Oxidation Catalysts

(2011) Yurii V. Geletii et al.   ISRAEL JOURNAL OF CHEMISTRY

Photoinduced Stepwise Oxidative Activation of a Chromophore–Catalyst Assembly on TiO2

(2011) Wenjing Song et al.   Journal of Physical Chemistry Letters

Distinguishing Homogeneous from Heterogeneous Catalysis in Electrode-Driven Water Oxidation with Molecular Iridium Complexes

(2011) Nathan D. Schley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Photocatalytic Properties of a New Heteropolyoxoniobate Compound: K10[Nb2O2(H2O)2][SiNb12O40]·12H2O

(2011) Zhenyu Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Characterization of a Metal-to-Polyoxometalate Charge Transfer Molecular Chromophore

(2011) Chongchao Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Co4O4“Cubane” Water Oxidation Catalyst Inspired by Photosynthesis

(2011) Nicholas S. McCool et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic Water Oxidation Beginning with the Cobalt Polyoxometalate [Co4(H2O)2(PW9O34)2]10–: Identification of Heterogeneous CoOxas the Dominant Catalyst

(2011) Jordan J. Stracke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Light-Driven Carbon-Free Cobalt-Based Molecular Catalyst for Water Oxidation

(2011) Zhuangqun Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Mechanism of Water Oxidation with Single-Site Ruthenium–Heteropolytungstate Complexes

(2011) Masato Murakami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient water oxidation catalysts based on readily available iron coordination complexes

(2011) Julio Lloret Fillol et al.   Nature Chemistry

Artificial Photosynthesis: From Molecular Catalysts for Light-driven Water Splitting to Photoelectrochemical Cells

(2011) Eugen S. Andreiadis et al.   PHOTOCHEMISTRY AND PHOTOBIOLOGY

Making solar fuels by artificial photosynthesis

(2011) Wenjing Song et al.   PURE AND APPLIED CHEMISTRY

The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis

(2010) Holger Dau et al.   ChemCatChem

Cs9[(γ-PW10O36)2Ru4O5(OH)(H2O)4], a new all-inorganic, soluble catalyst for the efficient visible-light-driven oxidation of water

(2010) Claire Besson et al.   CHEMICAL COMMUNICATIONS

Ruthenium polyoxometalate water splitting catalyst: very fast hole scavenging from photogenerated oxidants

(2010) Michele Orlandi et al.   CHEMICAL COMMUNICATIONS

Introduction: Proton-Coupled Electron Transfer

(2010) Sharon Hammes-Schiffer   CHEMICAL REVIEWS

Chemical and Photochemical Water Oxidation Catalyzed by Mononuclear Ruthenium Complexes with a Negatively Charged Tridentate Ligand

(2010) Lele Duan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rapid catalyticwateroxidation by a single site, Rucarbenecatalyst

(2010) Zuofeng Chen et al.   DALTON TRANSACTIONS

Substituents dependent capability of bis(ruthenium-dioxolene-terpyridine) complexes toward water oxidation

(2010) Tohru Wada et al.   DALTON TRANSACTIONS

Insight into Water Oxidation by Mononuclear Polypyridyl Ru Catalysts

(2010) Derek J. Wasylenko et al.   INORGANIC CHEMISTRY

Catalytic Water Oxidation by Single-Site Ruthenium Catalysts

(2010) Javier J. Concepcion et al.   INORGANIC CHEMISTRY

A New Family of Sandwich-Type Polytungstophosphates Containing Two Types of Metals in the Central Belt: M′2M2(PW9O34)212−(M′ = Na or Li, M = Mn2+, Co2+, Ni2+, and Zn2+)

(2010) Yu Hou et al.   INORGANIC CHEMISTRY

Synthesis of floriated ZnFe2O4 with porous nanorod structures and its photocatalytic hydrogen production under visible light

(2010) Hongjin Lv et al.   JOURNAL OF MATERIALS CHEMISTRY

Solar Driven Water Oxidation by a Bioinspired Manganese Molecular Catalyst

(2010) Robin Brimblecombe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fast Water Oxidation Using Iron

(2010) W. Chadwick Ellis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient water oxidation at carbon nanotube–polyoxometalate electrocatalytic interfaces

(2010) Francesca M. Toma et al.   Nature Chemistry

A Fast Soluble Carbon-Free Molecular Water Oxidation Catalyst Based on Abundant Metals

(2010) Q. Yin et al.   SCIENCE

Visible Light Water Splitting Using Dye-Sensitized Oxide Semiconductors

(2009) W. Justin Youngblood et al.   ACCOUNTS OF CHEMICAL RESEARCH

Hydrogen Evolution Catalyzed by Cobaloximes

(2009) Jillian L. Dempsey et al.   ACCOUNTS OF CHEMICAL RESEARCH

Artificial Photosynthesis and Solar Fuels

(2009) Leif Hammarström   ACCOUNTS OF CHEMICAL RESEARCH

The fossil energy/climate change crunch: Can we pin our hopes on new energy technologies?

(2009) C. Gonçalves da Silva   ENERGY

Structurally Characterized Iridium(III)-Containing Polytungstate and Catalytic Water Oxidation Activity

(2009) Rui Cao et al.   INORGANIC CHEMISTRY

Computational Studies of the Geometry and Electronic Structure of an All-Inorganic and Homogeneous Tetra-Ru-Polyoxotungstate Catalyst for Water Oxidation and Its Four Subsequent One-Electron Oxidized Forms

(2009) David Quiñonero et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Water Oxidation at a Tetraruthenate Core Stabilized by Polyoxometalate Ligands: Experimental and Computational Evidence To Trace the Competent Intermediates

(2009) Andrea Sartorel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dioxygen and Water Activation Processes on Multi-Ru-Substituted Polyoxometalates: Comparison with the “Blue-Dimer” Water Oxidation Catalyst

(2009) Aleksey E. Kuznetsov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural, Physicochemical, and Reactivity Properties of an All-Inorganic, Highly Active Tetraruthenium Homogeneous Catalyst for Water Oxidation

(2009) Yurii V. Geletii et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evidence for Pt(II)-Based Molecular Catalysis in the Thermal Reduction of Water into Molecular Hydrogen

(2009) Kosei Yamauchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homogeneous Light-Driven Water Oxidation Catalyzed by a Tetraruthenium Complex with All Inorganic Ligands

(2009) Yurii V. Geletii et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoassisted Overall Water Splitting in a Visible Light-Absorbing Dye-Sensitized Photoelectrochemical Cell

(2009) W. Justin Youngblood et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Hydrogenases to Noble Metal-Free Catalytic Nanomaterials for H2 Production and Uptake

(2009) A. Le Goff et al.   SCIENCE

Recent progress in the immobilization of catalysts for selective oxidation in the liquid phase

(2008) Luc Alaerts et al.   CHEMICAL COMMUNICATIONS

Photosynthetic energy conversion: natural and artificial

(2008) James Barber   CHEMICAL SOCIETY REVIEWS

Heterogeneous photocatalyst materials for water splitting

(2008) Akihiko Kudo et al.   CHEMICAL SOCIETY REVIEWS

When will fossil fuel reserves be diminished?

(2008) Shahriar Shafiee et al.   ENERGY POLICY

Homogeneous Catalytic System for Photoinduced Hydrogen Production Utilizing Iridium and Rhodium Complexes

(2008) Eric D. Cline et al.   INORGANIC CHEMISTRY

Polyoxometalate Embedding of a Tetraruthenium(IV)-oxo-core by Template-Directed Metalation of [γ-SiW10O36]8−: A Totally Inorganic Oxygen-Evolving Catalyst

(2008) Andrea Sartorel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY