4.5 Article

Synthesis and Structure of [Et3NH][Fe(HL)2] [H3L = L-2-(3,5-Di-tert-butyl-2-hydroxybenzylamino)succinic Acid] and Its Catalytic Activity towards Efficient Photodegradation of Dyes in the Presence of H2O2

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EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 30, 页码 5125-5134

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201402314

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Photodegradation; Green chemistry; Dyes; pigments; Iron; Amino acids; Biomimetic synthesis

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A new biogenic potentially tetradentate ligand, L-2-(3,5-di-tert-butyl-2-hydroxybenzylamino)succinic acid, has been synthesized. Upon reaction with FeCl3 in the presence of triethylamine, it afforded the complex [Et3NH][Fe(HL)(2)] (1). The complex was structurally characterized and was used for homogeneous photocatalytic degradation of methylene blue (MB), malachite green (MG), crystal violet (CV) and rhodamine B (RhB) under visible-light irradiation in aqueous solution in the presence of H2O2.

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