Article
Chemistry, Organic
Marina Yu. Dvorko, Dmitrii A. Shabalin, Igor A. Ushakov, Elena Yu. Schmidt, Boris A. Trofimov
Summary: The cascade dimerization of alkynones with sterically hindered secondary alkyl groups at the carbonyl function unexpectedly produced highly functionalized furans. This reaction efficiently takes place at room temperature in the presence of a potassium tert-butoxide/dimethylsulfoxide superbase catalytic system. Alkynones with an additional C-H active site at the carbon-carbon triple bond followed a different dimerization pathway to form 3-alkenylpyran-4-ones. The discovery of these reactions expands the traditional understanding of alkynone reactivity in strong basic conditions.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
Zhao-Bo Hou, Wei-Lin Xie, Gui-Xiang Liu, Shuangquan Liao, Ming-Chao Luo
Summary: Sulfur cross-linking, or vulcanization, is crucial in the rubber industry to enhance the properties of rubbers. However, the steric hindrance of vulcanization intermediates limits the formation of vulcanization networks and hinders property enhancement. This study demonstrates that reducing the steric hindrance of vulcanization intermediates promotes the formation of vulcanization networks, leading to significant improvements in the properties of vulcanized rubbers. This work provides a simple and generic strategy for developing high-performance rubbers.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Chemistry, Inorganic & Nuclear
Guotao Wang, Qixia Bai, Hui Liu, Zhengguang Li, Zhiyuan Jiang, Zhe Zhang, Yiming Li, Pingshan Wang
Summary: We achieved the adjustable self-assembly of metallosupramolecular cages by utilizing the steric hindrance effect, which allows for the precise control of their shape and size.
INORGANIC CHEMISTRY
(2023)
Article
Engineering, Environmental
Ziwen Ying, Minghui Chen, Guixuan Wu, Jie Li, Jilin Liu, Qifeng Wei, Xiulian Ren
Summary: The study developed an efficient way to separate vanadium (V) and chromium (VI) in weak acid solution using the steric hindrance effect of amide extractants. The recoveries of vanadium and chromium were high, with a purity of 99.97% for V2O5. The V(V) complex of amide was confirmed to be R2H6V10O28, and the extraction mechanism involved ion association with hydrogen bonding.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Review
Chemistry, Inorganic & Nuclear
Nathan T. Coles, Anne Sofie Abels, Julia Leitl, Robert Wolf, Hansjoerg Gruetzmacher, Christian Mueller
Summary: This review summarizes the progress made in the coordination chemistry of 1-phosphinines, 1,4-diphosphinines and 1,3,5-triphosphinines and related ligands over the past 10 years. It emphasizes the reactivity and application of phosphinine-containing transition metal complexes, as well as the electronic, structural and coordination properties of the corresponding phosphorus heterocycle.
COORDINATION CHEMISTRY REVIEWS
(2021)
Article
Engineering, Chemical
Meixian Liu, Junliang Liu, Zequan Zeng, Xing Wang, Jianfeng Jia, Xianmo Gu, Zhanfeng Zheng
Summary: Photopurification, a technique for substance purification, achieves selective mineralization through surface modification. By co-modification of nitrogen vacancies (NV) and cyano groups (-CN) on polymeric carbon nitride (PCN), benzaldehyde (BZ) in industrial styrene oxide (SO) production solution can be selectively photomineralized. This work not only provides a modification method for selective oxidation reactions, but also offers a new technique for removing homogeneous trace impurities in natural or industrial products.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Biology
Ponoop Prasad Patro, Thenmalarchelvi Rathinavelan
Summary: Biomolecular structural knowledge is crucial for understanding biological processes and diseases. In silico modeling, such as STRIDER, plays a vital role in designing and docking bio-macromolecules, as well as exploring their conformational dynamics. STRIDER estimates and reports steric hindrance and metal coordination, making it useful for flexible docking, protein folding, and structure-based virtual screening. It provides valuable insights for offline analysis.
COMPUTATIONAL BIOLOGY AND CHEMISTRY
(2022)
Article
Chemistry, Physical
Stefano Racioppi, Laura Orian, Cristina Tubaro, Armando Gennaro, Abdirisak Ahmed Isse
Summary: The equilibrium of copper-catalyzed atom transfer radical polymerization was investigated using computer simulation to explain the observed solvent effect. The study found that a continuum model for solvation was not sufficient, but including solvent molecules in the coordination sphere of the copper species and using a continuum description of the medium yielded a solvent-dependent thermodynamics in agreement with experimental trends.
Article
Chemistry, Multidisciplinary
Dianlong Zhao, Ming Cong, Zhun Liu, Zhiwei Ma, Kai Wang, Guanjun Xiao, Bo Zou
Summary: This study reveals the quantitative steric hindrance effect of different organic components in hybrid perovskites and successfully prepares 2D hybrid perovskite (NAPH)2PbCl4 nanoplates using 1-(2-naphthyl)methanamine. The research also demonstrates the reversal phenomenon of pressure-induced emission and establishes the correlation between PIE retention and steric hindrance, providing improved material design and synthesis for applications in white light-emitting diodes and scintillators.
CELL REPORTS PHYSICAL SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Quentin Dherbassy, Srimanta Manna, Chunling Shi, Watcharapon Prasitwatcharakorn, Giacomo E. M. Crisenza, Gregory J. P. Perry, David J. Procter
Summary: In this study, an enantioselective copper-catalyzed borylative cyclization was reported for the assembly of privileged pyrroloquinazolinone motifs. The reaction demonstrated high enantio- and diastereocontrol, yielding products with quaternary stereocenters. The utility of the products was further demonstrated through additional manipulations.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Applied
Tong Zhang, Yanning Han, Qiao Chen, Xinyu Chen, Pengchong Xue
Summary: The study found that substituents had little effect on absorption and emission properties in solution, but had an influence in crystal states; the size of terminal substituents was related to the photophysical properties in crystal states.
Article
Chemistry, Physical
Sen Liu, Maohuai Wang, Shuxian Wei, Siyuan Liu, Zhaojie Wang, Chi-Man Lawrence Wu, Daofeng Sun, Xiaoqing Lu
Summary: The study explored the use of metal-organic frameworks (MOFs) as CO2 capture adsorbents. It was found that by introducing functional groups, modifying pore size, and considering steric hindrance, the CO2 capture performance of MOFs can be significantly enhanced. The highest CO2 capture capacity was achieved by UPC-OSO3-steric, with selectivities of 1142.41 (CO2 over N2) and 507.42 (CO2 over CH4) at 1.0 bar, 298 K. The mechanisms of the synergistic effects were elucidated through theoretical calculations analyzing pore characteristics, gas distribution, and intermolecular interactions.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Plant Sciences
Julita Minasiewicz, Adrian Zwolicki, Tomas Figura, Alzbeta Novotna, Melissa F. Bocayuva, Jana Jersakova, Marc-Andre Selosse
Summary: This study examined the C:N:P stoichiometry of temperate orchids and found that the trophic mode of plants influences their elemental composition. The results suggest that mycoheterotrophic orchids have higher nutrient requirements compared to other mycoheterotrophic plants, which may result in higher fungal specificity. These findings provide insights into the evolution of nutrient acquisition in mycoheterotrophic plants.
Article
Energy & Fuels
Mamutjan Tursun, Chao Wu
Summary: This study investigates the activities of single-point defective 1T'-MoX2 (X = S, Se, Te) monolayers for electrocatalytic nitrogen reduction and nitric oxide reduction. The results show that both vacancy and antisite defects can serve as active sites, with antisite defects performing better for nitrogen reduction reaction and vacancy defects performing better for nitric oxide reduction reaction. The catalysts also exhibit selectivity towards ammonia production. The activity difference among the catalysts is mainly attributed to steric hindrance and electronic properties represented by work function.
Article
Chemistry, Organic
Axel Sabourin, Jeremy Dufour, Jean-Pierre Vors, David Bernier, Jean-Luc Montchamp
Summary: This study presents the synthesis of N- and C-substituted benzophostams. N-substitution was achieved by alkylation using a heterocycle, LiHMDS, and alkyl halide, or by copper-catalyzed cyclization of N-alkyl phosphonamide. N-Arylation could be accomplished either on the preformed heterocycle or on the phosphonamide precursor via copper-catalyzed cross-coupling. Dimethylation at the benzylic position was conducted using LiHMDS and methyl iodide, or a palladium-catalyzed reductive Heck reaction as a cost-effective and efficient alternative.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
(2022)
Article
Chemistry, Analytical
Anton S. Abel, Alexei D. Averin, Andrey V. Cheprakov, Irina P. Beletskaya, Michel Meyer, Alla Bessmertnykh-Lemeune
Summary: This work focuses on the development of water-soluble optical sensors based on ruthenium(II) tris(diimine) complexes, which have high molar absorptivity and emit light in aqueous media. The structures of these complexes can be easily modified to detect various analytes. As an example, an emissive complex was prepared for the selective detection of Cu2+ ions with low limits of detection.
Article
Zoology
Severine L. D. Toussaint, Jasper Ponstein, Mathieu Thoury, Remi Metivier, Daniela C. Kalthoff, Benoit Habermeyer, Roger Guilard, Steffen Bock, Peter Mortensen, Sverre Sandberg, Pierre Gueriau, Eli Amson
Summary: Photoluminescence (PL) examples are increasingly being observed in various organisms, but the underlying chemical basis and ecological function of PL are still poorly understood. Recent analyses in mammals have identified free-base porphyrins as the compounds responsible for reddish ultraviolet-induced PL observed in the pelage of springhares and hedgehogs. The localization of these pigments within the hair is still to be determined. In this study, photoluminescence multispectral imaging emission and excitation spectroscopy were used to detect, map, and characterize porphyrinic compounds in skin appendages. New cases of mammalian UV-PL caused by free-base porphyrins in distantly related species were also documented. The spatial distribution of UV-PL suggests an endogenous origin of the porphyrinic compounds. We argue that reddish UV-PL is predominantly observed in crepuscular and nocturnal mammals due to photodegradability of porphyrins, and thus this phenomenon may represent a byproduct of widespread physiological processes rather than serving a specific function in intra- or interspecific communication.
INTEGRATIVE ZOOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Nans Roques, Anthony Tovar-Molle, Carine Duhayon, Stephane Brandes, Alex Spiess, Christoph Janiak, Jean-Pascal Sutter
Summary: Five isostructural microporous supramolecular architectures with different R groups were obtained by H-bonded assembly, and a three-component H-bonded porous framework was successfully achieved using a mixture of tripodal cations with different R groups. The materials have pore diameters ranging from 3.0 to 8.5 angstrom and the sorption properties are influenced by the R groups.
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Chemistry, Analytical
Elizaveta Ermakova, Andrey Cheprakov, Alla Bessmertnykh-Lemeune
Summary: This research focuses on the development of pH indicators based on the quinoxaline signaling group for measuring acidic aqueous solutions (pH 1-5). A specific quinoxaline derivative, QC1, with hydrophilizing substituents was synthesized and found to be soluble in water within the pH range of interest. This derivative exhibits shifts in absorption and emission bands in response to external stimuli, making it suitable for optical measurements. It is also capable of detecting metal cations without interference and can be easily observed with the naked eye, allowing for rapid semi-quantitative analyses.
Article
Chemistry, Multidisciplinary
Nicolas Desbois, W. Ryan Osterloh, Dimitri Sabat, Camille Monot, Stephane Brandes, Michel Meyer, Capucine Chaar, Louise Hespel, Laurent Lebrun, Rachid Baati, Francois Estour, Claude P. P. Gros
Summary: A novel cobalt corrole with vinylphenyl groups at the meso-positions has been synthesized and its spectral and electrochemical properties, as well as its ability to form stable complexes and cross-linked polymer, have been studied. The yield of the polymerization reaction was 59%.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Tatevik Chilingaryan, Adrien Schlachter, Celine Frochot, B. Habermeyer, Pierre D. Harvey, Roger Guilard
Summary: New porous materials based on various porphyrin derivatives have been successfully incorporated into mesoporous silica MCM-41. The incorporation has been confirmed through UV-Vis spectroscopy and TGA. The mesoporous structure of MCM-41 remains unchanged after encapsulation, and the photosensitizers are mainly placed at the surface of the particles.
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
(2023)
Article
Chemistry, Physical
Varvara I. Fomenko, Arina V. Murashkina, Alexei D. Averin, Anastasiya A. Shesterkina, Irina P. Beletskaya
Summary: Commercially available copper and copper (II) oxide nanoparticles were characterized using TEM and electronography methods. The catalytic amine arylation using unsupported copper nanoparticles of different sizes and oxidation states was investigated, and CuNPs of average size 25 and 10/80 nm with ligands L1 and L2 were found to be the most versatile and efficient nanocatalysts. Investigation on copper leaching under different conditions was carried out.
Article
Chemistry, Inorganic & Nuclear
Pawel Jewula, Mickael Grandmougin, Melanie Choppin, Anna Maria Chiara Tivelli, Agnese Amati, Yoann Rousselin, Lydia Karmazin, Jean-Claude Chambron, Michel Meyer
Summary: Six- and seven-membered cyclic hydroxamic acids are commonly found in siderophores and can act as terminal binding units. However, the coordination chemistry of these ligands with Fe3+, the target metal ion of siderophores, has not been previously investigated. In this study, four complexes were synthesized and studied, and X-ray diffraction analysis showed that the AZEPO(-) complexes had better minimized interligand repulsion energies and shorter Fe-O bond distances compared to the PIPO complexes.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Tereza Edlova, Adrien T. Normand, Helene Cattey, Stephane Brandes, Yue Wu, Ariana Antonangelo, Benjamin Theron, Quentin Bonnin, Mariolino Carta, Pierre Le Gendre
Summary: Four cationic amidotitanocene complexes were synthesised and undergo Ti-N bond homolysis under visible light irradiation. Complexes 1a-c catalyse the polymerisation of phenylsilane to yield branched polysilane polymers with controlled molecular weights and dispersity indexes. Previously reported Group 4 cationic amidometallocene complexes were tested in the hydrosilylation reaction, with IIa showing higher selectivity and activity.
Article
Chemistry, Analytical
Elizaveta V. Ermakova, Anastasia V. Bol'shakova, Alla Bessmertnykh-Lemeune
Summary: This study focuses on the development of optical sensors for acidity measurements in low-pH aqueous solutions. Different hydrophilic-lipophilic balance (HLB) quinoxalines were prepared and investigated as molecular components of pH sensors. Immobilization of these quinoxalines in agarose and Langmuir-Blodgett (LB) and Langmuir-Schafer (LS) techniques allows for the fabrication of pH responsive polymers, paper test strips, and emissive films with excellent stability. These dual-responsive pH sensors enhance the accuracy of pH measurements, particularly in complex environmental samples.
Article
Chemistry, Physical
Inna A. Abdulaeva, Kirill P. Birin, Remi Chassagnon, Alla Bessmertnykh-Lemeune
Summary: Heterogenized metalloporphyrin catalysts were immobilized on hydrated mesoporous titanium dioxide through carboxylate or phosphonate anchoring groups. The element composition of the obtained mesoporous materials was investigated and the integrity of the immobilized complexes was confirmed. The catalytic efficiency of the more stable material Mn(TMPIP)/TiO2 with the phosphonate anchor was evaluated in the selective oxidation of sulfides to sulfoxides, showing excellent catalytic activity.
Article
Chemistry, Multidisciplinary
J. Yang, L. Andre, N. Desbois, C. P. Gros, S. Brandes
Summary: In this study, the synthesis, characterization, and gas adsorption properties of new 2D and 3D covalent organic frameworks (COFs) based on corrole macrocycles were reported. The materials were synthesized using readily available aldehyde as platforms and diamine-functionalized free-base corrole as building block linker. Cobalt-metalated COFs were also synthesized to obtain porous materials. The structure and performance of the materials for carbon monoxide (CO) adsorption were investigated using various spectroscopy analyses and sorption measurements. The results showed that 2D-COF-CorCo exhibited the highest adsorption capacity for CO with high selectivity over other gases.
MATERIALS TODAY CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Gleb V. Morozkov, Anton S. Abel, Konstantin A. Lyssenko, Vitaly A. Roznyatovsky, Alexei D. Averin, Irina P. Beletskaya, Alla Bessmertnykh-Lemeune
Summary: In this study, four mixed-ligand Ru(II) complexes were synthesized and characterized. It was found that the emission spectra of these complexes in aqueous solutions varied depending on the substitution position of the heterocycle. Among them, Ru-4,7PHEt exhibited higher photocatalytic efficiency and could be recycled through water extraction.
DALTON TRANSACTIONS
(2023)
Article
Materials Science, Multidisciplinary
Anton S. Abel, Andrey Cheprakov, Alexei D. Averin, Irina P. Beletskaya, Michel Meyer, Stephane Brandes, Myriam Laly, Alla Bessmertnykh-Lemeune, Severinne Rigolet
Summary: This study focuses on the development of synthetic approaches to luminescent organic-inorganic materials for the detection of toxic metal ions in aqueous solutions. The unique phosphonate-substituted ruthenium complexes were shown to have high sensitivity towards copper ions, offering a promising solution for solid-state sensors.
JOURNAL OF MATERIALS CHEMISTRY C
(2022)