期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 19, 页码 3010-3015出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201402150
关键词
Boron; Nitrides; Nanostructures; Copper oxide; Photoelectron spectroscopy; Aqueous dispersibility; X-ray diffraction
资金
- National Natural Science Foundation of China [21106006]
- Fundamental Research Funds for the Central Universities [ZZ1205]
Spherical boron nitride nanoparticles with good aqueous dispersibility were synthesized by means of a direct reaction of boric acid and ammonium chloride. The X-ray powder diffraction pattern confirmed the hexagonal BN structure (hBN) with d(002) = 3.33 angstrom. Copper oxide (CuO) was found to affect the morphology and surface properties of the BN nanoparticles. The average size of the spherical h-BN nanoparticles synthesized with the addition of CuO was about 30 nm. The h-BN had a high surface area of 75 m(2)g(-1) and a mesoporous volume of 0.32 cm(3)g(-1). The presence of CuO during the synthesis could enhance the surface electronegativity of the h-BN nanoparticles and change their isoelectric point to pH = 2.7. The zeta potentials of BN were between -30 and -50 mV in the pH range of 4-10. The h-BN nanoparticles were well dispersed and stable in aqueous solution.
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