4.5 Article

P4 Activation by Lanthanum and Lutetium Naphthalene Complexes Supported by a Ferrocene Diamide Ligand

期刊

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 2013, 期 22-23, 页码 4090-4096

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201300225

关键词

Zintl anions; Phosphorus; Lanthanum; Lutetium; Ferrocenes; Arene ligands

资金

  1. Sloan Foundation
  2. National Science Foundation (NSF) (CAREER project)
  3. NSF [CHE-1048804]
  4. Direct For Mathematical & Physical Scien
  5. Division Of Chemistry [0847735] Funding Source: National Science Foundation
  6. Division Of Chemistry
  7. Direct For Mathematical & Physical Scien [1048804] Funding Source: National Science Foundation

向作者/读者索取更多资源

Two rare-earth (La and Lu) naphthalene complexes supported by a ferrocene diamide ligand activate P-4 under ambient conditions to form M3P7 species exclusively. The resulting complexes feature a Zintl-type polyphosphide P-7(3-) unit stabilized by three lanthanide fragments. The reported metal complexes were characterized by X-ray crystallography, multinuclear NMR spectroscopy, and elemental analysis.

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