期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 2013, 期 22-23, 页码 4090-4096出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201300225
关键词
Zintl anions; Phosphorus; Lanthanum; Lutetium; Ferrocenes; Arene ligands
资金
- Sloan Foundation
- National Science Foundation (NSF) (CAREER project)
- NSF [CHE-1048804]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0847735] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1048804] Funding Source: National Science Foundation
Two rare-earth (La and Lu) naphthalene complexes supported by a ferrocene diamide ligand activate P-4 under ambient conditions to form M3P7 species exclusively. The resulting complexes feature a Zintl-type polyphosphide P-7(3-) unit stabilized by three lanthanide fragments. The reported metal complexes were characterized by X-ray crystallography, multinuclear NMR spectroscopy, and elemental analysis.
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