期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 16, 页码 2930-2939出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201300161
关键词
Homogeneous catalysis; CC coupling; Diene ligands; Rhodium
A novel synthetic route based on [4+2] cycloaddition for dibromobenzobarrelene derivatives starting from in situ generated 3,5-dibromo-1,2-didehydrobenzene and mesitylene, 1,2,4,5-tetramethylbenzene, 1,2,3,5-tetramethylbenzene, pentamethylbenzene, 1,3-dimethoxybenzene, and 2,4,6-trimethylbromobenzene, respectively, was developed. Thus, six novel dibromobenzobarrelenes with diverse substitution patterns at the barrelene framework including chiral derivatives are reported. The benzobarrelene 6,8-dibromo-1,3,10-trimethyl-1,4-dihydro-1,4-ethenonaphthalene (1a) was functionalized at the annulated benzene ring to give three novel carboxylic acids and two novel phosphonic acid esters. Selected benzobarrelene complexes with RhICl were tested for their catalytic activity in the 1,4-addition of phenylboronic acid towards cyclohex-2-enone. Turnover frequencies up to 3405 h1 were observed, which are among the highest reported so far for Rhdiene complexes in this type of CC coupling reaction.
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